Syngas production via bi-reforming of methane using transition metal based catalysts / (Record no. 104990)

MARC details
000 -LEADER
fixed length control field 03383ntm a2200349 i 4500
003 - CONTROL NUMBER IDENTIFIER
control field MY-KuUP
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20260612122245.0
006 - FIXED-LENGTH DATA ELEMENTS--ADDITIONAL MATERIAL CHARACTERISTICS
fixed length control field t|||||r|||| 000 0
007 - PHYSICAL DESCRIPTION FIXED FIELD--GENERAL INFORMATION
fixed length control field ta
008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION
fixed length control field 260612t20242024my a|||fr|||| 000 0 eng d
020 ## - INTERNATIONAL STANDARD BOOK NUMBER
International Standard Book Number THE0010600 (Local)
Qualifying information Hardback
040 ## - CATALOGING SOURCE
Original cataloging agency UMPSA
Language of cataloging eng
Transcribing agency UMPSA
Description conventions rda
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) FTKKP .Y44 2024 r Bc.
100 0# - MAIN ENTRY--PERSONAL NAME
Personal name Heng, Yee Phang,
Relator term author.
245 10 - TITLE STATEMENT
Title Syngas production via bi-reforming of methane using transition metal based catalysts /
Statement of responsibility, etc. Heng Yee Phang
264 #1 - PRODUCTION, PUBLICATION, DISTRIBUTION, MANUFACTURE, AND COPYRIGHT NOTICE
Place of production, publication, distribution, manufacture Kuantan, Pahang :
Name of producer, publisher, distributor, manufacturer UMPSA,
Date of production, publication, distribution, manufacture, or copyright notice 2024
264 #4 - PRODUCTION, PUBLICATION, DISTRIBUTION, MANUFACTURE, AND COPYRIGHT NOTICE
Date of production, publication, distribution, manufacture, or copyright notice © 2024
300 ## - PHYSICAL DESCRIPTION
Extent xv, 41 pages :
Other physical details illustrations ;
336 ## - CONTENT TYPE
Source rdacontent
Content type term text
337 ## - MEDIA TYPE
Source rdamedia
Media type term unmediated
338 ## - CARRIER TYPE
Source rdacarrier
Carrier type term volume
347 ## - DIGITAL FILE CHARACTERISTICS
Source rda
File type text file
Encoding format PDF
500 ## - GENERAL NOTE
General note Faculty of Chemical and Process Engineering Technology
502 ## - DISSERTATION NOTE
Dissertation note Final Year Report (Bachelor of Chemical Engineering ) -- Universiti Malaysia Pahang Al-Sultan Abdullah - 2024
504 ## - BIBLIOGRAPHY, ETC. NOTE
Bibliography, etc. note Include bibliographical reference
520 3# - SUMMARY, ETC.
Summary, etc. Amidst global concerns over greenhouse gas emissions and fossil fuel depletion, the exploration of clean and sustainable energy became paramount. This research explored the field of methane bi-reforming, an innovative process that simultaneously produced syngas and reduced emissions of both methane and carbon dioxide. Catalyst deactivation in bi-reforming posed challenges, necessitating optimization for enhanced efficiency. This research priortized Ni and Co catalysts because of their balance between effectiveness and affordability. Hence, mono-metallic (Ni and Co) and bi-metallic (Ni-Co) were evaluated via bi-reforming of methane in this study. Three catalysts, 15%Ni/CeO2-CaO, 15%Co/CeO2-CaO and 7.5%Ni-7.5%Co/CeO2-CaO were synthesized using an ultrasonic impregnation-assisted technique and employed in bi-reforming of methane reaction for 8 hours. XRD, BET, SEM and TPO analysis were used to characterize the catalyst. Performance studies were conducted with different catalyst and temperature settings. In accordance with BET analysis, 7.5%Ni-7.5%Co/CeO2-CaO catalyst, possessing the largest surface area, demonstrated the greatest catalytic activity. The results from bi-reforming of methane reaction indicated 7.5%Ni-7.5%Co/CeO2-CaO catalyst displayed superior performance. This was evident in its high conversions, reaching 84% and 92% for CH4 and CO2 respectively, at a temperature of 800°C. Temperature variation experiments on the bi-metallic catalyst identified 900°C as optimal, achieving 91% CH4 conversion and 75% CO2 conversion. Unexpectedly, the high temperature resulting high ratio of H2/CO. This can be explained by the basic support provided by CeO2-CaO, facilitating the adsorption of CO2 while preventing reverse water gas shift reaction from producing CO. Post-reaction XRD on the spent catalyst at 800°C revealed crystalline graphite structures associated with carbon deposition while a lower degree of graphitization at lower temperatures. TPO analysis demonstrated that the bi-metallic catalyst had a high catalytic activity by showing significant amount of graphitic carbon had been deposited on its surface.
610 20 - SUBJECT ADDED ENTRY--CORPORATE NAME
Corporate name or jurisdiction name as entry element Faculty of Chemical and Process Engineering Technology
General subdivision Dissertations
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Universities and colleges
General subdivision Dissertations
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Theses
General subdivision Dissertations
856 ## - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier
942 ## - ADDED ENTRY ELEMENTS (KOHA)
Source of classification or shelving scheme Library of Congress Classification
Koha item type Final Year Report
Holdings
Withdrawn status Lost status Source of classification or shelving scheme Damaged status Not for loan Permanent Location Current Location Date acquired Total Checkouts Full call number Barcode Date last seen Price effective from Koha item type
  Not lost Library of Congress Classification     UMPLIB GAMBANG UMPLIB GAMBANG 12/06/2026   FTKKP .Y44 2024 r Bc. T000004139 12/06/2026 12/06/2026 Restricted Collection

Perpustakaan Universiti Malaysia Pahang Al-Sultan Abdullah
26600 Pekan, Pahang Darul Makmur
Phone: +609 431 5063 (Gambang) / +609 431 5035 (Pekan)
Email: umplibrary@umpsa.edu.my

Connect With Us