Effect of different mesostructured material based on silica (TiO2, SBA-15 and CAB-O-SIL) as cobalt supports for fischer-tropsch synthesis / (Record no. 3731)

MARC details
000 -LEADER
fixed length control field 03494nam a2200265 a 4500
001 - CONTROL NUMBER
control field vtls000068145
003 - CONTROL NUMBER IDENTIFIER
control field KUKTEM
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20251114204533.0
008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION
fixed length control field 130121t2012 my a f m 000 0 eng d
020 ## - INTERNATIONAL STANDARD BOOK NUMBER
International Standard Book Number THE0004220(Local)
039 #9 - LEVEL OF BIBLIOGRAPHIC CONTROL AND CODING DETAIL [OBSOLETE]
Level of rules in bibliographic description 201905152035
Level of effort used to assign nonsubject heading access points farhana
-- 201301211244
-- Fida
040 ## - CATALOGING SOURCE
Original cataloging agency UMP
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) TP159.C3 I77 2012 rs Bc.
100 0# - MAIN ENTRY--PERSONAL NAME
Personal name Mohamad Irsyad Mohamad Mazuki
245 10 - TITLE STATEMENT
Title Effect of different mesostructured material based on silica (TiO2, SBA-15 and CAB-O-SIL) as cobalt supports for fischer-tropsch synthesis /
Statement of responsibility, etc. Mohamad Irsyad Mohamad Mazuki
260 ## - PUBLICATION, DISTRIBUTION, ETC.
Place of publication, distribution, etc. Kuantan, Pahang :
Name of publisher, distributor, etc. UMP,
Date of publication, distribution, etc. 2012
300 ## - PHYSICAL DESCRIPTION
Extent x, 43 p. :
Other physical details ill. ;
Dimensions 30 cm. +
Accompanying material 1 CD-ROM
502 ## - DISSERTATION NOTE
Dissertation note Project paper (Bachelor of Chemical Engineering (Gas Technology)) -- Universiti Malaysia Pahang - 2012
504 ## - BIBLIOGRAPHY, ETC. NOTE
Bibliography, etc. note Bibliography : p. 41-43
520 3# - SUMMARY, ETC.
Summary, etc. The research was about the synthesis of active and selective for syngas processing via Fischer–Tropsch synthesis (FTS) producing clean and best fuel. A series of 20 wt. % cobalt catalysts be prepared by impregnation of a mesoporous molecular sieve based on silica as 75 wt. % of cobalt catalytic supporters (SBA-15, TiO and CabO-Sil) with 5 wt. % Zn promoter for comparison purposes. All materials used characterizing by several analysis equipments which are SEM, TGA and FTIR. The characterization results achieve gave a great influence of mesoporous support porosity on the structure, reducibility of cobalt oxide species supported over the selected materials. Firstly, the experiment was started from the synthesis of SBA-15. TiO2 and Cab-O-Sil are commercialized support. Then, the silica as cobalt supporters were synthesized by incipient wetness impregnation method of using mixture of Cobalt (II) Nitrate and Zinc Nitrate Hexahydrate solution. Next, the prepared catalysts were calcined at 350°C for 6 h by increasing the temperature at a controlled heating rate of 2°C/min. The characterization of catalysts and catalyst studies was performed. The result from experiment was SBA-15 supporter shown the better result compared to other samples as the microscopic size captured by SEM equipment prove that SBA-15 had smoothest and smallest of mesoporous surface size. The result from FTIR showed that the peak at around 3,440 cm-1 have the hydroxyl groups and about 1,630 cm -12 is due to the bending vibrations of O-H bonds that the percentage reflectance of O-H bonds which indicates the SBA-15 can effectively restrain the loss of surface hydroxyl groups during calcinations. The peak around 1000-1200 cm1 can be assigned to the siloxane or Si-O-Si stretching bands; peak appears as a broad and strong peaking the sample. Lastly, TGA result showed that SBA-15 can help the catalyst samples restrained more water content in the evaporation process and had high thermal stability that can prolong life at high temperature and high pressure in the Fischer-Tropsch synthesis. The new silica as cobalt supporter will be developed to enhance the performance of the best and clean fuel production. This research hopefully can be carried out successful in order to get the new invention for production of catalyst that will produce the best and clean fuel and to get rid of exceed cost of production but in the same quality of expensive product.
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Catalysts
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Fischer-Tropsch process
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Catalysis
Holdings
Withdrawn status Lost status Damaged status Not for loan Home library Current library Date acquired Total checkouts Full call number Barcode Date last seen Copy number Price effective from Koha item type
  Not lost   Not for loan UMPLIB GAMBANG UMPLIB GAMBANG 04/09/2019   TP159.C3 I77 2012 rs Bc. 0000068467 04/09/2019 1 04/09/2019 Final Year Report
  Not lost   Not for loan UMPLIB GAMBANG UMPLIB GAMBANG 04/09/2019   CD 6450 | TP159.C3 I77 2012 rs Bc. 0000068468 04/09/2019 1 04/09/2019 Final Year Report

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