Hydrogen and methane production from palm oil mill effluent through two-stage dark fermentation / (Record no. 4561)

MARC details
000 -LEADER
fixed length control field 04866ntm a2200277 a 4500
001 - CONTROL NUMBER
control field vtls000101619
003 - CONTROL NUMBER IDENTIFIER
control field KUKTEM
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20251114204601.0
008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION
fixed length control field 171005t2017 my a f abm 000 0 eng d
020 ## - INTERNATIONAL STANDARD BOOK NUMBER
International Standard Book Number THE0001418(Local)
039 #9 - LEVEL OF BIBLIOGRAPHIC CONTROL AND CODING DETAIL [OBSOLETE]
Level of rules in bibliographic description 201905211226
Level of effort used to assign nonsubject heading access points asmadi
Level of effort used to assign subject headings 201711061658
Level of effort used to assign classification nazri
-- 201710051052
-- nazri
040 ## - CATALOGING SOURCE
Original cataloging agency UMP
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) FTeK .S26 2017 r Thesis
100 0# - MAIN ENTRY--PERSONAL NAME
Personal name Santhana Krishnan Chandrasekar
245 10 - TITLE STATEMENT
Title Hydrogen and methane production from palm oil mill effluent through two-stage dark fermentation /
Statement of responsibility, etc. Santhana Krishnan Chandrasekar
260 ## - PUBLICATION, DISTRIBUTION, ETC.
Place of publication, distribution, etc. Kuantan, Pahang :
Name of publisher, distributor, etc. UMP,
Date of publication, distribution, etc. 2017
300 ## - PHYSICAL DESCRIPTION
Extent xvii, 161 p. :
Other physical details ill. (some col.) ;
Dimensions 30 cm. +
Accompanying material 1 CD-ROM
500 ## - GENERAL NOTE
General note Faculty of Engineering Technology
502 ## - DISSERTATION NOTE
Dissertation note Thesis (Doctor of Philosophy in Energy and Environmental Engineering) -- Universiti Malaysia Pahang – 2017
504 ## - BIBLIOGRAPHY, ETC. NOTE
Bibliography, etc. note Bibliography : p. 133-149
520 3# - SUMMARY, ETC.
Summary, etc. Two-stage dark fermentation is a green technology, presents an outstanding opportunity for both high energy conversion and pollution control. The main objective of this research is to investigate two-stage dark fermentation processes for sequential hydrogen (H2) and methane (CH4) production using palm oil mill effluent (POME) in up-flow anaerobic sludge blanket–continuous stirred tank reactor (UASB-CSTR). During the experiment, H2 was produced in UASB reactor at thermophilic condition (55ºC) in the first stage, while CH4 was produced from the effluents of UASB reactor in the CSTR at mesophilic condition (37ºC) in the second stage. The heat treated and non-heat treated anaerobic sludge was used as inoculum for UASB and CSTR reactor, respectively. In the first study, batch test was conducted to find out the hydrogen production potential (HPP) and methane production potential (MPP) of POME. Following, the UASB reactor operated continuously at thermophilic conditions with the hydraulic retention time (HRT) of 2 days and organic loading rate (OLR) 75 kgCOD m3ˑd-1 for H2 production. The effluents from UASB reactor were directly fed into CSTR for CH4 production at mesophilic temperature with the HRT of 5 days. The maximum H2 and CH4 production rate achieved was 1.92 L H2 L-1d-1 and 3.2 L CH4 L-1 d-1, respectively. The cumulative H2 and CH4 yields were 215 L H2/kgCOD-1 and 320 L CH4/kgCOD-1, respectively with the total COD removal efficiency of 94%. The sludge granules from both UASB and CSTR reactor were analyzed using scanning electron microscopy and the microbial community was analyzed using polymerase chain reaction denaturing gradient gel electrophoresis (PCR-DGGE). Results revealed that sludge granules were nearly round shaped with multiple cracks on the surface and UASB and CSTR reactor was enriched with Thermoanaerobacterium species and Methanobrevibacter species, Methanosarcina species, repectively. The second study addressed the effect of recirculation of methane effluent into UASB reactor for the continuous H2 and CH4 production. HPP from POME mixed with methanogenic effluent at recirculation rate of 50%, 40%, 35%, 30%, 20% and 10% was investigated. The recirculation of methanogenic effluent at 35% recirculation rate could compensate for alkalinity required by UASB reactor. The maximum H2 and CH4 yield were 178 mL H2/gCOD and 412 mL CH4/gCOD, respectively. Two-stage process with methanogenic effluent recirculation flavoured the UASB reactor and efficiently for energy recovery from POME. In the third study, influence of different organic loading rates (OLR) such as 25, 50, 75, 100, 125 kg-COD/m3∙d was analyzed for the improvement of hydrogen and methane production rate and yield. The better yield was achieved when the OLR was in the range of 75 kg-COD/m3∙d. The maximum H2 production rate was 175.15 mL H2/g MLVSS∙d, while the highest H2 content and yield were 35% and 49.22 mL H2/g CODapplied, respectively. The maximum CH4 content, CH4 yield, and specific methane production rate (SMPR) were 68%, 155.87 mL CH4/g CODapplied and 325.13 mL CH4/g MLVSS∙d, respectively. The results indicated that OLR affected H2-CH4 production and substrate removal efficiency. Finally, the studies on the influence of flow rate (QF) and up-flow velocity (Vup) ranging (1.7-10.2 L/d) and (0.5-3.0 m/h), respectively on hydrogen production using response surface methodology (RSM) showed that H2 yield was 0.32 L H2 g-1 COD at QF and Vup of 1.7 L d-1 and 0.5 m h-1, respectively The optimum ranges for the fermentative hydrogen production of the POME were QF = 2.1-3.7 L/d and Vup =1.5-2.3 m/h. The experimental results agreed very well with the model prediction.
610 20 - SUBJECT ADDED ENTRY--CORPORATE NAME
Corporate name or jurisdiction name as entry element Faculty of Engineering Technology
General subdivision Dissertations
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Universities and Colleges
General subdivision Dissertations
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Theses
Holdings
Withdrawn status Lost status Source of classification or shelving scheme Damaged status Not for loan Home library Current library Date acquired Total checkouts Full call number Barcode Date last seen Copy number Price effective from Koha item type
  Not lost Library of Congress Classification   Not for loan UMPLIB GAMBANG UMPLIB GAMBANG 04/09/2019   FTeK .S26 2017 r Thesis 0000119709 04/09/2019 1 04/09/2019 Thesis
  Not lost Library of Congress Classification   Not for loan UMPLIB GAMBANG UMPLIB GAMBANG 04/09/2019   CD 10820 | FTeK .S26 2017 r Thesis 0000119710 04/09/2019 1 04/09/2019 Thesis

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