Production of mixed-matrix membrane (psf/zeolite) for co2 / n2 separation: (Record no. 5311)

MARC details
000 -LEADER
fixed length control field 03327ntm a2200253 a 4500
001 - CONTROL NUMBER
control field vtls000084888
003 - CONTROL NUMBER IDENTIFIER
control field KUKTEM
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20251117113236.0
008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION
fixed length control field 150115t2014 my a f m 000 0 eng d
020 ## - INTERNATIONAL STANDARD BOOK NUMBER
International Standard Book Number THE0004567(Local)
039 #9 - LEVEL OF BIBLIOGRAPHIC CONTROL AND CODING DETAIL [OBSOLETE]
Level of rules in bibliographic description 201905141121
Level of effort used to assign nonsubject heading access points azhar
-- 201501151734
-- fawwaz
040 ## - CATALOGING SOURCE
Original cataloging agency UMP
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) TP350 .C44 2014 r Bc.
100 3# - MAIN ENTRY--PERSONAL NAME
Personal name Chen, Chee Lek
245 10 - TITLE STATEMENT
Title Production of mixed-matrix membrane (psf/zeolite) for co2 / n2 separation:
Remainder of title screening study of polymer concentration /
Statement of responsibility, etc. Chen Chee Lek
260 ## - PUBLICATION, DISTRIBUTION, ETC.
Place of publication, distribution, etc. Kuantan, Pahang :
Name of publisher, distributor, etc. UMP,
Date of publication, distribution, etc. 2014
300 ## - PHYSICAL DESCRIPTION
Extent xvii, 84 p. :
Other physical details ill. ;
Dimensions 30 cm. +
Accompanying material 1 CD-ROM
500 ## - GENERAL NOTE
General note Faculty of Chemical & Natural Resources Engineering
502 ## - DISSERTATION NOTE
Dissertation note Project paper (Bachelor of Chemical Engineering) -- Universiti Malaysia Pahang – 2014
504 ## - BIBLIOGRAPHY, ETC. NOTE
Bibliography, etc. note Bibliography : p. 65-84
520 3# - SUMMARY, ETC.
Summary, etc. This research investigated the permeability of CO2 and N2 as well as selectivity of CO2 over N2 of polysulfone (PSF) mixed matrix membranes filled with zeolite 4Å particles. The mixed matrix membrane was prepared by immersion precipitation method with zeolite and PSf were ranged from 10 to 30 W/V% dissolved in the NMP varied from 75 to 100 cm3. The mixture was then mixed homogenously and utilized to determine the permeation rates of N2 and CO2. It is characterized by FTIR and the gas separation performance is analysed by Design of Expert (DOE) method. In accordance to our expectation, FTIR results revealed that the intensity at 3596.17 cm−1 described the existence of an interaction between polymer and zeolite. The permeability of CO2 through the membrane was in higher range from 9.873 to 11.641 GPU. At lower operating pressure, the greater solubility of gas encourages a higher permeation rate. The single concentration variable has low effect, however the interaction between PSf and NMP (BC) has considerable effect on the permeability of CO2 with the highest F value of 0.46. NMP exhibited a high degree of polarity and hydrogen bonding which led to effect of selective skin and permeation rate. The more solvent evaporated, the thicker the concentrated polymer region which then leads to a thicker selective skin and a reduction in permeation rate. The interaction of zeolite and PSf had the least significant effect on the selectivity of CO2 over N2 due to the lower F value with 0.023, however the interaction had higher permeability of CO2 with the F value of 0.45. The cause of low permeability of CO2 was poor association between the zeolite and the polymer leading to an increased in free volume within the membrane. Although it enhanced the permeability of CO2, but it limited the sieving mechanism which resulted low selectivity of CO2 over N2. The model regression equations were evaluated by F-test ANOVA which revealed that these regressions are statistically significant at 95% confidence level to screening the permeability of CO2 and N2 as well as selectivity of CO2/N2. In future research, optimisation is proposed based on the screening study of PSf and zeolite concentration ranged from 22.30 to 27.45 W/V% to stress on the high permeability and selectivity CO2/N2 separation membranes
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Carbon dioxide
Holdings
Withdrawn status Lost status Damaged status Not for loan Home library Current library Date acquired Total checkouts Full call number Barcode Date last seen Copy number Price effective from Koha item type
  Not lost   Not for loan UMPLIB GAMBANG UMPLIB GAMBANG 04/09/2019   TP350 .C44 2014 r Bc. 0000091505 04/09/2019 1 04/09/2019 Final Year Report
  Not lost   Not for loan UMPLIB GAMBANG UMPLIB GAMBANG 04/09/2019   CD 8526 | TP350 .C44 2014 r Bc. 0000091506 04/09/2019 1 04/09/2019 Final Year Report

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