Hydrogen production from CO2 reforming of methane over cobalt-based catalysts / (Record no. 6029)

MARC details
000 -LEADER
fixed length control field 03176nam a2200265 a 4500
001 - CONTROL NUMBER
control field vtls000091281
003 - CONTROL NUMBER IDENTIFIER
control field KUKTEM
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20251117113259.0
008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION
fixed length control field 150922t2015 my a f m 000 0 eng d
020 ## - INTERNATIONAL STANDARD BOOK NUMBER
International Standard Book Number THE0004227(Local)
039 #9 - LEVEL OF BIBLIOGRAPHIC CONTROL AND CODING DETAIL [OBSOLETE]
Level of rules in bibliographic description 201905152045
Level of effort used to assign nonsubject heading access points farhana
Level of effort used to assign subject headings 201712061046
Level of effort used to assign classification huda
-- 201509221228
-- huda
040 ## - CATALOGING SOURCE
Original cataloging agency UMP
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) TP159.C3 T36 2015 r Bc.
100 1# - MAIN ENTRY--PERSONAL NAME
Personal name Tan, Ji Siang
245 1# - TITLE STATEMENT
Title Hydrogen production from CO2 reforming of methane over cobalt-based catalysts /
Statement of responsibility, etc. Tan Ji Siang
260 ## - PUBLICATION, DISTRIBUTION, ETC.
Place of publication, distribution, etc. Kuantan, Pahang :
Name of publisher, distributor, etc. UMP,
Date of publication, distribution, etc. 2015
300 ## - PHYSICAL DESCRIPTION
Extent xviii, 108 p. :
Other physical details ill. (some col.) ;
Dimensions 30 cm. +
Accompanying material 1 CD ROM
500 ## - GENERAL NOTE
General note Faculty of Chemical & Natural Resources Engineering
502 ## - DISSERTATION NOTE
Dissertation note Project paper (Bachelor of Chemical Engineering) -- Universiti malaysia Pahang - 2015
504 ## - BIBLIOGRAPHY, ETC. NOTE
Bibliography, etc. note Biobliography : p. 89-99
520 3# - SUMMARY, ETC.
Summary, etc. Increased concerns on anthropogenic greenhouse gas emissions have renewed interest in the CO2 (dry) reforming process as an alternative to steam reforming for synthesis gas production from natural gas. For hydrocarbon dry reforming, where the product stream H2:CO ratio is less than 3, synfuel production is more amenable and acceptable for downstream methanol and other oxygenated synthesis. However, dry reforming is highly endothermic, and suffers from carbon-induced catalyst deactivation. This thesis therefore investigates and evaluates the performance of methane dry reforming process at different operation conditions such as reaction temperature and feed composition, and the effects of loaded metals (Mo and Ni) on alumina-supported Co-based catalyst. Runs of the methane dry reforming experiment were conducted in a computer-controlled fixebed reactor at different feed compositions and reaction temperature. Both MoO3 and NiO phases were formed during wetness co-impregnation with a mixture of deionized water and alumina support as measured in X-ray diffraction. Temperature-programmed calcination showed that the transformations from MoO3 to CoMoO4 phase and NiO to NiAl2O4 phase were a 2 step process involving the formation of an oxidation intermediate form. Calcination of co-impregnated catalysts at 500 0C for 5 h appeared to be optimal preparation condition for H2 selectivity. Al2O3 support was the best support to give the highest H2 to CO ratio. Second metal promotion did not alter reaction rate significantly. However the interaction of loaded metal oxides with the surface carbonaceous species resulted in substantially reduced carbon deposition on Co-based catalyst, with Ni providing the greatest coking resistance compared to Mo. A quantitative relationship between activation energy and feed composition of CO2:CH4 ( 1:1, 2:1 and 3:1 ) as well as reaction temperatures (923 K, 953 K and 973 K) was obtained over bimetallic 5%Ni-10%Co/Al2O3 catalyst which gave the highest value of H2/CO ratio in the methane dry reforming process. Methane dry reforming activity was stable with time-on-stream for 4 h.
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Catalysts
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="http://ecollib.ump.edu.my/9555/">http://ecollib.ump.edu.my/9555/</a>
Public note Access in library only
Holdings
Withdrawn status Lost status Damaged status Not for loan Home library Current library Date acquired Total checkouts Full call number Barcode Date last seen Copy number Price effective from Koha item type
  Not lost   Not for loan UMPLIB GAMBANG UMPLIB GAMBANG 04/09/2019   TP159.C3 T36 2015 r Bc. 0000100641 04/09/2019 1 04/09/2019 Final Year Report
  Not lost   In Transit UMPLIB GAMBANG UMPLIB GAMBANG 04/09/2019   CD 8976 | TP159.C3 T36 2015 r Bc. 0000100642 04/09/2019 1 04/09/2019 Final Year Report

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