Evaluative study of glycerol photocatalytic degradation over CuFe2O4 AND La-CuFe2O4 photocatalysts / (Record no. 6096)

MARC details
000 -LEADER
fixed length control field 03243ntm a2200277 a 4500
001 - CONTROL NUMBER
control field vtls000091210
003 - CONTROL NUMBER IDENTIFIER
control field KUKTEM
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20251117113302.0
008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION
fixed length control field 150910t2015 my da f m 000 0 eng d
020 ## - INTERNATIONAL STANDARD BOOK NUMBER
International Standard Book Number THE0002194(Local)
039 #9 - LEVEL OF BIBLIOGRAPHIC CONTROL AND CODING DETAIL [OBSOLETE]
Level of rules in bibliographic description 201905131715
Level of effort used to assign nonsubject heading access points yusri
Level of effort used to assign subject headings 201711281513
Level of effort used to assign classification saini
-- 201509101636
-- huda
040 ## - CATALOGING SOURCE
Original cataloging agency UMP
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) QD716.P45 T36 2015 r Bc.
100 1# - MAIN ENTRY--PERSONAL NAME
Personal name Tan, Sze Yee
245 10 - TITLE STATEMENT
Title Evaluative study of glycerol photocatalytic degradation over CuFe2O4 AND La-CuFe2O4 photocatalysts /
Statement of responsibility, etc. Tan Sze Yee
260 ## - PUBLICATION, DISTRIBUTION, ETC.
Place of publication, distribution, etc. Kuantan, Pahang :
Name of publisher, distributor, etc. UMP,
Date of publication, distribution, etc. 2015
300 ## - PHYSICAL DESCRIPTION
Extent xiv, 88 p. :
Other physical details ill. (some col.) ;
Dimensions 30 cm. +
Accompanying material 1 CD-ROM
500 ## - GENERAL NOTE
General note Faculty of Chemical & Natural Resources Engineering
502 ## - DISSERTATION NOTE
Dissertation note Project paper (Bachelor of Chemical Engineering) -- Universiti Malaysia Pahang - 2015
504 ## - BIBLIOGRAPHY, ETC. NOTE
Bibliography, etc. note Bibliography : p. 63-67
520 3# - SUMMARY, ETC.
Summary, etc. Glycerol is produced as a side product (10 wt %) during biodiesel synthesis. If left untreated, it can potentially degrade the environment. Moreover, its purification is cost-prohibitive. This study therefore aims to investigate the physicochemical properties of copper ferrite, CuFe2O4 for the photocatalysis of glycerol. The CuFe2O4 was synthesized employing co-precipitation method, with and without lanthanum dopant (La) to enhance the catalytic properties of the photocatalyst. Characterization of the physiochemical properties was carried out using He displacement, N2 physisorption, Field Emission Scanning Electron Microscope (FESEM) and X-ray Diffraction (XRD). The characterization results revealed that the CuFe2O4 synthesized had a density of 2.4953 g/cm3 while La-CuFe2O4’s density was 3.4734 g/cm3. CuFe2O4 showed better catalyst characterization than La-CuFe2O4 by showing higher pore volume and surface area of 0.1683 cm3/g and 102.37 m2/g, respectively. XRD results proved the CuFe2O4 crystal to be face-centered cubic. The photocatalytic degradation of 0.5 v/v % glycerol under visible light irradiation (Xenon lamp with wavelength 400-700 nm) over copper ferrite (30 wt % Cu) and copper ferrite doped with lanthanum (40 wt % La) was carried out to determine the effectiveness of the catalyst. The amount of hydrogen peroxide (H2O2) added to create a Fenton system was varied to determine the effect of H2O2 in the effectiveness of photodegradation. In the preliminary assessment of photoactivity property of CuFe2O4, it was found that CuFe2O4 can effectively degrade methylene blue (an organic dye). Nevertheless, it exhibited insignificant photocatalytic effect on glycerol. Significantly, it can be shown that by adding a minimum of 0.5 mL H2O2 (photo-Fenton system), photocatalytic degradation of glycerol can take place, whilst up to 1.0 mL H2O2 was required for significant glycerol degradation over La-CuFe2O4. The rate and extent of glycerol degradation increased with the amount of H2O2. This study has therefore proved that CuFe2O4 can degrade glycerol under visible light source in a photo-Fenton reaction.
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Photocatalysis
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Glycerols
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="http://ecollib.ump.edu.my/id/eprint/25664">http://ecollib.ump.edu.my/id/eprint/25664</a>
Public note Access in library only
Holdings
Withdrawn status Lost status Damaged status Not for loan Home library Current library Date acquired Total checkouts Full call number Barcode Date last seen Copy number Price effective from Koha item type
  Not lost   Not for loan UMPLIB GAMBANG UMPLIB GAMBANG 04/09/2019   QD716.P45 T36 2015 r Bc. 0000100528 04/09/2019 1 04/09/2019 Final Year Report
  Not lost   In Transit UMPLIB GAMBANG UMPLIB GAMBANG 04/09/2019   CD 8921 | QD716.P45 T36 2015 r Bc. 0000100529 04/09/2019 1 04/09/2019 Final Year Report

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