Synthesis and characterization of EFB clinker supported nickel and cobalt catalysts for methane dry reforming / (Record no. 6107)

MARC details
000 -LEADER
fixed length control field 02758ntm a2200265 a 4500
001 - CONTROL NUMBER
control field vtls000091204
003 - CONTROL NUMBER IDENTIFIER
control field KUKTEM
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20251117113302.0
008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION
fixed length control field 150910t2015 my da f m 000 0 eng d
020 ## - INTERNATIONAL STANDARD BOOK NUMBER
International Standard Book Number THE0004214(Local)
039 #9 - LEVEL OF BIBLIOGRAPHIC CONTROL AND CODING DETAIL [OBSOLETE]
Level of rules in bibliographic description 201905152032
Level of effort used to assign nonsubject heading access points farhana
-- 201509101214
-- huda
040 ## - CATALOGING SOURCE
Original cataloging agency UMP
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) TP159.C3 C43 2015 r Bc.
100 1# - MAIN ENTRY--PERSONAL NAME
Personal name Chan, Han Jie
245 1# - TITLE STATEMENT
Title Synthesis and characterization of EFB clinker supported nickel and cobalt catalysts for methane dry reforming /
Statement of responsibility, etc. Chan Han Jie
260 ## - PUBLICATION, DISTRIBUTION, ETC.
Place of publication, distribution, etc. Kuantan, Pahang :
Name of publisher, distributor, etc. UMP,
Date of publication, distribution, etc. 2015
300 ## - PHYSICAL DESCRIPTION
Extent xvi, 80 p. :
Other physical details ill. (some col.) ;
Dimensions 30 cm. +
Accompanying material 1 CD-ROM
500 ## - GENERAL NOTE
General note Faculty of Chemical & Natural Resources Engineering
502 ## - DISSERTATION NOTE
Dissertation note Project paper (Bachelor of Chemical Engineering) -- Universiti Malaysia Pahang - 2015
504 ## - BIBLIOGRAPHY, ETC. NOTE
Bibliography, etc. note Bibliography : p. 56-59
520 3# - SUMMARY, ETC.
Summary, etc. Methane dry reforming is environmental friendly due to the potential sequestration of CO2. Therefore, substantial research works have been carried out to develop reforming catalysts that exhibit high catalytic performance and excellent longevity. The current work reports on the synthesis of 20wt%Co/80wt%EFB clinker and 20wt%Ni/80wt%EFB clinker catalysts via wet-impregnation technique, followed by various characterization techniques such as BET, XRD, XRF, TGA and FESEM. The BET specific surface area of Co/EFB clinker and Ni/EFB clinker catalyst were 2.83 m2g-1 and 2.37 m2g-1, respectively. In addition, XRD diffractogram of EFB clinker showed two highest peaks at around 2θ = 27.2° and 31.5°, which can be attributed to CaO and K2O species, respectively. This finding was also consistent with XRF analysis where potassium (K) and calcium (Ca) were positively identified. Subsequently, methane dry reforming studies revealed that Ni/EFB clinker catalyst always yielded higher formation rates of H2 and CO. Indeed, the rate was maximum at CO2:CH4 feed ratio of unity. The average conversion of CH4 for reactions using Co/EFB clinker and Ni/EFB clinker catalyst are obtained to be 78.26 % and 78.19 % respectively. Meanwhile, the average conversion of CO2 for reactions using Co/EFB clinker and Ni/EFB clinker catalyst are 80.40 % and 81.17 % respectively. When reaction temperatures were varied, the activation energy over Co/EFB clinker was 124.4 kJ mol-1 while that for the reaction over the Ni/EFB clinker catalyst was 113.0 kJ mol-1. Post reforming reaction, oxidation profiles of the used catalysts indicated carbon-free condition. This was corroborated by the FESEM images for both sets of used catalysts, where no carbon whisker was found.
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Catalysts
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Methane
Holdings
Withdrawn status Lost status Damaged status Not for loan Home library Current library Date acquired Total checkouts Full call number Barcode Date last seen Copy number Price effective from Koha item type
  Not lost   Not for loan UMPLIB GAMBANG UMPLIB GAMBANG 04/09/2019   TP159.C3 C43 2015 r Bc. 0000100546 04/09/2019 1 04/09/2019 Final Year Report
  Not lost   In Transit UMPLIB GAMBANG UMPLIB GAMBANG 04/09/2019   CD 8930 | TP159.C3 C43 2015 r Bc. 0000100547 04/09/2019 1 04/09/2019 Final Year Report

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