Ethanol dry reforming for h2 production over lanthanide-group promoted Co/Al2O3 catalysts / (Record no. 6569)

MARC details
000 -LEADER
fixed length control field 03618ntm a2200289 a 4500
001 - CONTROL NUMBER
control field vtls000093548
003 - CONTROL NUMBER IDENTIFIER
control field KUKTEM
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20251117113319.0
008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION
fixed length control field 160307t2015 my a f 000 0 eng d
020 ## - INTERNATIONAL STANDARD BOOK NUMBER
International Standard Book Number THE0001032(Local)
039 #9 - LEVEL OF BIBLIOGRAPHIC CONTROL AND CODING DETAIL [OBSOLETE]
Level of rules in bibliographic description 201905241000
Level of effort used to assign nonsubject heading access points nazirah
Level of effort used to assign subject headings 201712071540
Level of effort used to assign classification nazri
Level of effort used to assign subject headings 201603071159
Level of effort used to assign classification huda
-- 201603071104
-- huda
040 ## - CATALOGING SOURCE
Original cataloging agency UMP
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) FKKSA .T35 2015 r Bc.
100 1# - MAIN ENTRY--PERSONAL NAME
Personal name Tai, Chan Kong
245 1# - TITLE STATEMENT
Title Ethanol dry reforming for h2 production over lanthanide-group promoted Co/Al2O3 catalysts /
Statement of responsibility, etc. Tai Chan Kong
260 ## - PUBLICATION, DISTRIBUTION, ETC.
Place of publication, distribution, etc. Kuantan, Pahang :
Name of publisher, distributor, etc. UMP,
Date of publication, distribution, etc. 2015
300 ## - PHYSICAL DESCRIPTION
Extent xiii, 74 p. :
Other physical details ill. ;
Dimensions 30 cm. +
Accompanying material 1 CD-ROM
500 ## - GENERAL NOTE
General note Faculty of Chemical & Natural Resources Engineering
502 ## - DISSERTATION NOTE
Dissertation note Project Paper (Bachelors of Chemical Engineering (Gas Technology)) -- Universiti Malaysia Pahang – 2015
504 ## - BIBLIOGRAPHY, ETC. NOTE
Bibliography, etc. note Bibliography : p. 60-63
520 3# - SUMMARY, ETC.
Summary, etc. This paper presents the studies of the La-group promoter addition effects and their performances. Three different catalysts are synthesized with addition of different promoters supported by alumina. The catalysts are synthesized by using the wet impregnation process, which involved dissolving and mixing specific calculated amount of nitrate salts and calcined alumina in distilled water. The solutions are then stirred for 3 consecutive hours before they are dried in the oven for 12hrs. Lastly, the catalysts are calcined in a furnace at 1023K for 5 consecutive hours to remove remaining water content and nitrates. The calcined and uncalcined catalysts were collected for catalyst characterization analysis which involved, Thermalgrametric Analysis (TGA), Scanning Electron Microscopy (SEM), Brunauer Emmett Teller (BET) and X-ray Diffraction Analysis (XRD). Calcined unreduced catalysts were used for ethanol dry reforming syngas production reaction runs at conditions of temperature 973K, pressure 1 atm, and 1:1 C2H5OH to CO2 ratio. The content of the produced syngas were analyzed using gas chromatography, and the results were compared between the catalysts for their performances. XRD analysis showed that the second metal promotion did not affect the original structure of catalyst. The SEM analysis indicates addition of cerium and lanthanum as promoters affected the morphology of the catalyst by altering the surface texture by introducing flakes to the molecular surface of the promoted catalysts. Addition of La-group promoters is capable to provide stable catalytic performance and slightly improved C2H5OH and CH4 conversion into syngas mixture of H2 and CO when compare to non-promoted cobalt catalyst. The promoter addition decreases/slow-down the process of carbon decomposition on the catalysts’ surfaces in the order; La > Ce > non-promoted Co/Al2O3 catalysts together boosts up the production of H2 and CO gas in term of production rate, yield and also selectivity. The production output H2:CO ratio is very suitable for downstream production such as Fischer–Tropsch synthesis. The trend of CH4:CO ratio suggests catalytic reforming of methane from ethanol decomposition occurrence, where methane was converted into syngas mixture of CO and H2. The overall performances of catalysts increased by the promotion order, La > Ce > non-promoted Co/Al2O3 catalysts.
610 20 - SUBJECT ADDED ENTRY--CORPORATE NAME
Corporate name or jurisdiction name as entry element Faculty of Chemical & Natural Resources Engineering
General subdivision Dissertations
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Universities and Colleges
General subdivision Dissertations
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Theses
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="http://ecollib.ump.edu.my/25580/">http://ecollib.ump.edu.my/25580/</a>
Public note Access in library only
Holdings
Withdrawn status Lost status Damaged status Not for loan Home library Current library Date acquired Total checkouts Full call number Barcode Date last seen Copy number Price effective from Koha item type
  Not lost   Not for loan UMPLIB GAMBANG UMPLIB GAMBANG 04/09/2019   FKKSA .T35 2015 r Bc. 0000107653 04/09/2019 1 04/09/2019 Final Year Report
  Not lost   Not for loan UMPLIB GAMBANG UMPLIB GAMBANG 04/09/2019   CD 9589 | FKKSA .T35 2015 r Bc. 0000107654 04/09/2019 1 04/09/2019 Final Year Report

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