Synthesis,characterization and performance of triethanolamine-based thin film composite nanofiltration membrane/ (Record no. 6578)

MARC details
000 -LEADER
fixed length control field 04518ntm a2200289 a 4500
001 - CONTROL NUMBER
control field vtls000094202
003 - CONTROL NUMBER IDENTIFIER
control field KUKTEM
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20251117113319.0
008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION
fixed length control field 160330t2015 da f ab m 000 0 eng d
020 ## - INTERNATIONAL STANDARD BOOK NUMBER
International Standard Book Number THE0000980(Local)
039 #9 - LEVEL OF BIBLIOGRAPHIC CONTROL AND CODING DETAIL [OBSOLETE]
Level of rules in bibliographic description 201905241625
Level of effort used to assign nonsubject heading access points nazirah
Level of effort used to assign subject headings 201710111627
Level of effort used to assign classification aishah
-- 201603301613
-- shima
040 ## - CATALOGING SOURCE
Original cataloging agency UMP
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) FKKSA .N87 2015 r Thesis
100 0# - MAIN ENTRY--PERSONAL NAME
Personal name Nurul Ain Jalanni
245 1# - TITLE STATEMENT
Title Synthesis,characterization and performance of triethanolamine-based thin film composite nanofiltration membrane/
Statement of responsibility, etc. Nurul Ain Binti Jalanni
260 ## - PUBLICATION, DISTRIBUTION, ETC.
Place of publication, distribution, etc. Kuantan, Pahang :
Name of publisher, distributor, etc. UMP,
Date of publication, distribution, etc. 2015
300 ## - PHYSICAL DESCRIPTION
Extent xiii, 115 p. :
Other physical details ill. (some col. ;
Dimensions 30 cm. +
Accompanying material 1 CD-ROM
500 ## - GENERAL NOTE
General note Faculty of Chemical & Natural Resources Engineering
502 ## - DISSERTATION NOTE
Dissertation note Thesis (Master of Engineering (Chemical)) -- Universiti Malaysia Pahang – 2015
504 ## - BIBLIOGRAPHY, ETC. NOTE
Bibliography, etc. note Bibliography : p. 92-104
520 3# - SUMMARY, ETC.
Summary, etc. Humic acid (HA) is one of the common NOM which contribute a major problem in treatment of surface water including (i) negative effect on water quality by colour, taste and odour problems, (ii) increased coagulant and disinfectant dose requirement (iii) promoted biological growth in distribution system and (iv) increased levels of complexes heavy metals and adsorbed organic pollutants. Thus, more efficient method for the humic acid removal has emerged. Among the membrane processes, nanofiltration (NF) has been increasingly used for wastewater and water treatments including natural organic matters (NOM). Nine membranes were prepared through interfacial polymerization of aqueous solution, triethanolamine (TEOA) and organic solution, trimesoyl chloride (TMC) on a polyethersulfone (PES) support film. The composite membranes were prepared under different TEOA monomer concentration (4, 6, 8 % w/v) and reaction times (15, 25, and 35 min). These membranes were characterized in terms of chemical properties (functional group and hydrophilicity) and morphological structures to verify polyester membrane formed on the top surface of PES (interfacial polymerization process). On top of that, membrane performance was also investigated in term of pure water permeability, rejection of charged (sodium chloride (NaCl) and sodium sulphate (Na2SO4)) and uncharged solutes (vitamin B12). All nine polyester membranes showed NF characteristics which in between 12.98 L m2h-1bar-1until 1.25 L m2h-1bar-1. Analysis done by attenuated total reflectance fourier transform infrared spectroscopy (ATR-FTIR) on top surface and field emission scanning electron microscopy (FESEM) on top and cross sectional membrane indicate a new polyester layer formed on the PES membrane support. Highest TEOA monomer concentration (8% w/v TEOA) and reaction time membrane (35 min) resulted as less hydrophobicity membrane when achieved the lowest contact angle measurement (θ = 34.0 ± 0.35) compared to unmodified membrane (θ = 62.6 ± 0.33). Using uncharged (Vitamin B12)/charged solute (NaCl) data, the changes in the morphological and electrical properties of the synthesized NF membranes were deduced by employing the combination of irreversible thermodynamic model, Steric-Hindrance Pore (SHP) model and Teorell–Meyer–Sievers (TMS) model. In NF membrane characterization, three important parameters have been identified as an effective pore radius (rp), the ratio of effective thickness over porosity (Δx/Ak) and an effective charged density (Xd). In this study, it was observed that the variation of reaction times and TEOA monomer concentrations affect the properties of the membrane produced and affect water permeabilities and solute rejection as well. The salt rejection order of the membrane changed from 0.001 M Na2SO4> 0.1M Na2SO4> 0.001M NaCl> 0.1M NaCl. Moreover, pH of humic acid solution plays an important role in flux reduction and fouling. HA filtration analysis was preferably chosen at pH 7 (4% 35 min) and pH 3 (4% 15 min) respectively It observes that all nine membranes able to removes humic acid with an efficiency of approximately 98% and were capable of reducing initial concentrations of 15 mg/L at the TEOA monomer concentration (6% w/v TEOA) and reaction time (35 min).
610 20 - SUBJECT ADDED ENTRY--CORPORATE NAME
Corporate name or jurisdiction name as entry element Faculty of Chemical & Natural Resources Engineering
General subdivision Dissertations
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Universities and Colleges
General subdivision Dissertations
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Theses
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="http://ecollib.ump.edu.my/3546/">http://ecollib.ump.edu.my/3546/</a>
Public note Library access only
Holdings
Withdrawn status Lost status Source of classification or shelving scheme Damaged status Not for loan Home library Current library Date acquired Total checkouts Full call number Barcode Date last seen Copy number Price effective from Koha item type
  Not lost Library of Congress Classification   Not for loan UMPLIB GAMBANG UMPLIB GAMBANG 04/09/2019   FKKSA .N87 2015 r Thesis 0000107801 04/09/2019 1 04/09/2019 Thesis
  Not lost Library of Congress Classification   Not for loan UMPLIB GAMBANG UMPLIB GAMBANG 04/09/2019   CD 9660 | FKKSA .N87 2015 r Thesis 0000107802 04/09/2019 1 04/09/2019 Thesis

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