Titanium dioxide based hybrid photocatalyst for seawater desalination pre-treatment / (Record no. 6964)

MARC details
000 -LEADER
fixed length control field 04318ntm a2200289 a 4500
001 - CONTROL NUMBER
control field vtls000100038
003 - CONTROL NUMBER IDENTIFIER
control field KUKTEM
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20251117113333.0
008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION
fixed length control field 170504t2016 my da f abm 000 0 eng d
020 ## - INTERNATIONAL STANDARD BOOK NUMBER
International Standard Book Number THE0001042(Local)
039 #9 - LEVEL OF BIBLIOGRAPHIC CONTROL AND CODING DETAIL [OBSOLETE]
Level of rules in bibliographic description 201905171305
Level of effort used to assign nonsubject heading access points nazirah
Level of effort used to assign subject headings 201710161647
Level of effort used to assign classification aishah
-- 201705041441
-- saini
040 ## - CATALOGING SOURCE
Original cataloging agency UMP
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) FKKSA .W44 2016 r Thesis
100 0# - MAIN ENTRY--PERSONAL NAME
Personal name Weerana Eh Kan
245 10 - TITLE STATEMENT
Title Titanium dioxide based hybrid photocatalyst for seawater desalination pre-treatment /
Statement of responsibility, etc. Weerana Eh Kan
260 ## - PUBLICATION, DISTRIBUTION, ETC.
Place of publication, distribution, etc. Kuantan, Pahang :
Name of publisher, distributor, etc. UMP,
Date of publication, distribution, etc. 2016
300 ## - PHYSICAL DESCRIPTION
Extent xviii, 123 p. :
Other physical details ill. (some col.) ;
Dimensions 30 cm.
500 ## - GENERAL NOTE
General note Faculty of Chemical & Natural Resources Engineering
502 ## - DISSERTATION NOTE
Dissertation note Thesis (Master of Engineering in Chemical) -- Universiti Malaysia Pahang – 2016
504 ## - BIBLIOGRAPHY, ETC. NOTE
Bibliography, etc. note Bibliography : p. 109-119
520 3# - SUMMARY, ETC.
Summary, etc. The application of hybrid titanium dioxide (TiO2) photocatalyst in treating water resources has huge economic potential and an attractive alternative technology for seawater pre-desalination. The objective of this investigation is to study the effectiveness of photocatalytic reactor system via hybrid photocatalyst that content oil palm fiber ash (OPFA), TiO2 and metal promoter in the seawater desalination pre-treatment. The study was carried out in a one liter borosilicate photoreactor for 1 hr to 4 hrs. The catalyst to seawater sample weight ratio was varied from 1:300 to 1:500. The experiment was carried out by using mercury light (UV light) and halogen light (visible light). The chemical oxygen demand (COD), pH, dissolved oxygen (DO), turbidity, total dissolved solid (TDS) and conductivity of the seawater were analyzed prior and after the treatment. The fresh and spent catalysts were characterized via X-ray diffraction (XRD), scanning electron microscopy (SEM), N2 adsorption, ultraviolet visible near-UV/near-infrared (UV/Vis/Nir), elemental analysis (carbon, hydrogen, nitrogen and sulphur (CHNS)) and X-ray fluorescence (XRF). The gas product was analyzed by using gas chromatography with thermal conductivity detector (GC-TCD). The TiO2 catalyst can reduce salt concentration for more than 7 % and decrease up to 8 % of COD. The OPFA was able to adsorb about 3 % of salt in either with the present or absent of lights. Furthermore, OPFA reduced seawater COD for more than 10 % the light presence and 4 % in without light present. The hybrid catalyst containing TiO2:Ash 50:50 was calcined at 500 °C, reduced more than 9 % of salt and 24 % of COD reduction in the seawater. It is found that the TiO2:Ash 50:50 catalyst has dual functions, ie. the catalyst was able to adsorb the salt and decompose the water contaminants resulting in lower conductivity and COD in the seawater. However, the hybrid TiO2:Ash 50:50 catalyst which calcined at 800 °C was only able to reduce 2 % of salt and 14 % of COD reduction in the seawater. Better TiO2:Ash 50:50 catalyst reactivity was achieved when UV light was used than visible light. Higher water temperature was observed when visible light was applied that leads to distillation dominating the process. The optimum parameters for photocatalytic reaction was obtained by using hybrid TiO2:Ash 50:50 catalyst when catalyst to water weight ratio was at 1:400 and operating for 2 hrs. Iron (Fe) and nickel (Ni) can be loaded into the catalyst. Fe loading in the catalyst was found to perform better than Ni. The best condition was obtained when visible light and TiO2:Ash:Fe 47.5:47.5:5 were used. The TiO2:Ash:Fe 47.5:47.5:5 reduced 16 % and 22 % of salt concentration and COD respectively. While, the TiO2:Ash:Ni 47.5:47.5:5 was only able to reduce up to 13 % of salt in the seawater and decrease 22 % of seawater COD at the same condition. In conclusion, better water quality can be achieved via photocatalytic reaction by using hybrid photocatalyst. Thus, the photocatalysis process is able to provide an effective alternative pre-treatment for seawater desalination.
610 20 - SUBJECT ADDED ENTRY--CORPORATE NAME
Corporate name or jurisdiction name as entry element Faculty of Chemical & Natural Resources Engineering
General subdivision Dissertations
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Universities and Colleges
General subdivision Dissertations
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Theses
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="http://ecollib.ump.edu.my/25864/">http://ecollib.ump.edu.my/25864/</a>
Public note Library access only
Holdings
Withdrawn status Lost status Source of classification or shelving scheme Damaged status Not for loan Home library Current library Date acquired Total checkouts Full call number Barcode Date last seen Copy number Price effective from Koha item type
  Not lost Library of Congress Classification   Not for loan UMPLIB GAMBANG UMPLIB GAMBANG 04/09/2019   CD 10765 | FKKSA .W44 2016 r Thesis 0000117818 04/09/2019 1 04/09/2019 Thesis
  Not lost Library of Congress Classification   Not for loan UMPLIB GAMBANG UMPLIB GAMBANG 04/09/2019   FKKSA .W44 2016 r Thesis 0000117817 04/09/2019 1 04/09/2019 Thesis

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