Adsorption of hydrogen sulfide from simulated waste water using locally –sourced adsorbents / (Record no. 7989)

MARC details
000 -LEADER
fixed length control field 04117ntm a2200349 i 4500
001 - CONTROL NUMBER
control field vtls000104315
003 - CONTROL NUMBER IDENTIFIER
control field KUKTEM
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20251117113410.0
008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION
fixed length control field 180716s2018 my da f am 000 0 eng d
020 ## - INTERNATIONAL STANDARD BOOK NUMBER
International Standard Book Number THE0000893(Local)
039 #9 - LEVEL OF BIBLIOGRAPHIC CONTROL AND CODING DETAIL [OBSOLETE]
Level of rules in bibliographic description 201905271506
Level of effort used to assign nonsubject heading access points nazirah
-- 201807161604
-- saini
040 ## - CATALOGING SOURCE
Original cataloging agency UMP
Language of cataloging eng
Transcribing agency UMP
Description conventions rda
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) FKKSA .H33 2018 r Thesis
100 1# - MAIN ENTRY--PERSONAL NAME
Personal name Habeeb, Omar Abed,
Relator term author.
245 10 - TITLE STATEMENT
Title Adsorption of hydrogen sulfide from simulated waste water using locally –sourced adsorbents /
Statement of responsibility, etc. Omar Abed Habeeb
264 #1 - PRODUCTION, PUBLICATION, DISTRIBUTION, MANUFACTURE, AND COPYRIGHT NOTICE
Place of production, publication, distribution, manufacture Kuantan, Pahang :
Name of producer, publisher, distributor, manufacturer UMP,
Date of production, publication, distribution, manufacture, or copyright notice 2018
300 ## - PHYSICAL DESCRIPTION
Extent xviii, 173 pages :
Other physical details illustrations (some color), charts ;
Dimensions 30 cm. +
Accompanying material 1 CD-ROM
336 ## - CONTENT TYPE
Content type term text
Source rdacontent
337 ## - MEDIA TYPE
Media type term unmediated
Source rdamedia
337 ## - MEDIA TYPE
Media type term computer
Source rdamedia
338 ## - CARRIER TYPE
Carrier type term volume
Source rdacarrier
338 ## - CARRIER TYPE
Carrier type term computer disc
Source rdacarrier
347 ## - DIGITAL FILE CHARACTERISTICS
File type text file
Encoding format PDF
Source rda
500 ## - GENERAL NOTE
General note Faculty of Chemical and Natural Resources Engineering
502 ## - DISSERTATION NOTE
Dissertation note Thesis (Doctor of Philosophy in Chemical and Natural Resources Engineering) -- Universiti Malaysia Pahang – 2018
504 ## - BIBLIOGRAPHY, ETC. NOTE
Bibliography, etc. note Includes bibliographical references
520 3# - SUMMARY, ETC.
Summary, etc. Hydrogen sulfide (H2S) (aq) is one of the most toxic pollutants in petroleum refinery waste water. It is very harmful to human health and causes environmental and economic problems. The removal of H2S (aq) from a simulated petroleum refinery waste water using activated carbons produced from agricultural by-product such as, coconut shell (CNS), palm kernel shell (PKS), and wood sawdust (WSD) were investigated. The activated carbons obtained from the CNS, PKS, and WSD were chemically activated using KOH. The activated carbons (ACs) were modified by impregnating with calcium (Ca) extracted from egg shells to produce impregnated activated carbons (IACs) namely Ca-ACCNS, Ca-ACPKS and Ca-ACWSD. The prepared ACs and IACs were characterized using SEM/EDX, FTIR, BET, TGA, XRD and XPS. Comparative studies between all the six adsorbents for the removal of H2S (aq) from the simulated waste water were carried out. The adsorption studies revealed that Ca-modified PKS-based activated carbon (Ca-ACPKS) has shown best performance for the removal of H2S (aq). An optimization studies for the preparation conditions of the selected adsorbent (Ca-ACPKS) was investigated using Response Surface Methodology (RSM) and the optimum preparation conditions were found to be calcination temperature of 880 °C, calcium solution concentration of 49.31 %v, and calcination time of 57.5 min with removal efficiency of 99.2% and yield of 33.8%. Moreover, operating factors such as initial concentration of H2S (aq), adsorption contact time, dosage, pH of solution, and agitation speed were initially screened using 2 level factorial approach and the resulted significant factors were initial concentration of H2S (aq), adsorption contact time, and dosage were significant on the removal of H2S (aq). Furthermore, the effect of these three operating parameters were investigated using the central composite design (CCD) techniques of RSM and the optimum conditions obtained were initial concentration of H2S of 440 mg/L, adsorption contact time of 585 min, and dosage of 1.05 g Ca-ACPKS. The optimum operating conditions resulted in a removal efficiency of 99.5% with equilibrium concentration (0.5-2.2 mg/L) which was close to Department of Environment (DOE) standard B (0.5 mg/L) using real waste water. The kinetic studies of the adsorption behaviour of Ca-ACPKS have shown that Freundlich adsorption isotherm was fitted well and the adsorption process followed Pseudo- second order kinetic model. The maximum adsorption capacity of Ca-ACPKS was 543.4 mg/g. It can be concluded that Ca-ACPKS has an effective adsorbent for the removal of H2S (aq) from simulated waste water.
610 20 - SUBJECT ADDED ENTRY--CORPORATE NAME
Corporate name or jurisdiction name as entry element Faculty of Chemical & Natural Resources Engineering
General subdivision Dissertations
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Universities and colleges
General subdivision Disertations
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Theses
Holdings
Withdrawn status Lost status Source of classification or shelving scheme Damaged status Not for loan Home library Current library Date acquired Total checkouts Full call number Barcode Date last seen Copy number Price effective from Koha item type
  Not lost Library of Congress Classification   Not for loan UMPLIB GAMBANG UMPLIB GAMBANG 04/09/2019   FKKSA .H33 2018 r Thesis 0000123553 04/09/2019 1 04/09/2019 Thesis
  Not lost Library of Congress Classification   Not for loan UMPLIB GAMBANG UMPLIB GAMBANG 04/09/2019   CD 11367 | FKKSA .H33 2018 r Thesis 0000123554 04/09/2019 1 04/09/2019 Thesis

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