Removal of mercury (II) ion from industrial wastewater using palm oil fuel ash / (Record no. 7999)

MARC details
000 -LEADER
fixed length control field 04403ntm a2200373 i 4500
001 - CONTROL NUMBER
control field vtls000105333
003 - CONTROL NUMBER IDENTIFIER
control field KUKTEM
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20251117113411.0
008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION
fixed length control field 180928t20182018my da f a m 001 0 eng d
020 ## - INTERNATIONAL STANDARD BOOK NUMBER
International Standard Book Number THE0000916(Local)
039 #9 - LEVEL OF BIBLIOGRAPHIC CONTROL AND CODING DETAIL [OBSOLETE]
Level of rules in bibliographic description 201905271541
Level of effort used to assign nonsubject heading access points nazirah
-- 201809280941
-- fateeha
040 ## - CATALOGING SOURCE
Original cataloging agency UMP
Language of cataloging eng
Transcribing agency UMP
Description conventions rda
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) FKKSA .I45 2018 r Thesis
100 0# - MAIN ENTRY--PERSONAL NAME
Personal name Imla Syafiqah Mohd Salleh,
Relator term author.
245 10 - TITLE STATEMENT
Title Removal of mercury (II) ion from industrial wastewater using palm oil fuel ash /
Statement of responsibility, etc. Imla Syafiqah Mohd Salleh
264 #1 - PRODUCTION, PUBLICATION, DISTRIBUTION, MANUFACTURE, AND COPYRIGHT NOTICE
Place of production, publication, distribution, manufacture Kuantan, Pahang :
Name of producer, publisher, distributor, manufacturer UMP,
Date of production, publication, distribution, manufacture, or copyright notice 2018
264 #4 - PRODUCTION, PUBLICATION, DISTRIBUTION, MANUFACTURE, AND COPYRIGHT NOTICE
Date of production, publication, distribution, manufacture, or copyright notice © 2018
300 ## - PHYSICAL DESCRIPTION
Extent xv, 122 pages :
Other physical details illustrations (some color), charts ;
Dimensions 30 cm. +
Accompanying material 1 CD-ROM
336 ## - CONTENT TYPE
Content type term text
Source rdacontent
336 ## - CONTENT TYPE
Content type term text
Source rdacontent
337 ## - MEDIA TYPE
Media type term unmediated
Source rdamedia
337 ## - MEDIA TYPE
Media type term computer
Source rdamedia
338 ## - CARRIER TYPE
Carrier type term volume
Source rdacarrier
338 ## - CARRIER TYPE
Carrier type term computer disc
Source rdacarrier
347 ## - DIGITAL FILE CHARACTERISTICS
File type text file
Encoding format PDF
Source rda
500 ## - GENERAL NOTE
General note Faculty of Chemical & Natural Resources Engineering
502 ## - DISSERTATION NOTE
Dissertation note Thesis (Master of Science) -- Universiti Malaysia Pahang – 2018
504 ## - BIBLIOGRAPHY, ETC. NOTE
Bibliography, etc. note Includes bibliographical references
520 3# - SUMMARY, ETC.
Summary, etc. Activated palm oil fuel ashes (POFA) were used as the adsorbents for the removal of mercury (II) ion from industrial wastewater. From the preliminary experimental results, it shows that the POFA had good adsorption capability for mercury (II) ion. The adsorption process of mercury (II) ion using POFA not only contributes to the mercury adsorption from industrial wastewater but also removes the environmental pollution caused by accumulation and abundance of waste in nature. Therefore, POFA was introduced as a raw material in this study to maximize the utilization of oil palm waste. POFA was activated using chemical activation and sulphuric acid used as a solvent before proceeding with mercury (II) ion adsorption process. Scanning electron microscopy (SEM), fourier transform infrared spectrometry (FTIR), thermal gravimetric analysis (TGA), and Brunauer-Emmett-Teller (BET) surface area analysis had been applied to observe the effect of the POFA structure before and after activation. The screening study was analyzed using fractional factorial design (FFD). In factorial analysis study, the best mercury (II) ion removal condition removed 98.03 ± 0.06 % when performed at 100 rpm of agitation speed, pH 2, 5 mg/L of initial mercury (II) ion concentration, 0.25 g of adsorbent dosages and 4 h of contact time. From this screening study, two factors which are contact time and agitation speed were selected for further analysis in optimization part. The optimization of mercury (II) ion removal efficiency was done by using central composite design (CCD) in response surface methodology (RSM). In central composite design (CCD), the optimum condition for mercury (II) ion removal was obtained at 150 rpm for 5 h which removed 98.93 ± 0.02 % of mercury (II) ion. The equilibrium data at various concentrations were analysed by Langmuir and Freundlich isotherms models. From this present study, the values of correlation coefficient (R2) obtained from the Freundlich isotherm was 0.9899. A kinetic study was carried out with pseudo first order and pseudo second order reaction equations. It was found that the mercury (II) ion uptake process followed the pseudo second order rate expression. Thermodynamic parameters of the Gibbs free energy (Δ𝐺°), enthalpy (Δ𝐻°), and entropy (Δ𝑆°) were also determined. The negative Gibbs free energy change (-764.32 kJ/mol) and the positive enthalpy change (75531.86 kJ/mol) indicated that adsorption was spontaneous process and endothermic nature. It was found that activated POFA was a good adsorbent for mercury (II) ion removal with 91.18 % mercury removal from industrial wastewater. This result was comparable to other researcher in the range from 90 to 95 % mercury (II) ion removal. Overall, POFA has the potential to be used as an adsorbent for the removal of mercury (II) ion from industrial wastewater due to its high performance and availability at low cost.
610 20 - SUBJECT ADDED ENTRY--CORPORATE NAME
Corporate name or jurisdiction name as entry element Faculty of Chemical & Natural Resources Engineering
General subdivision Dissertations
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Universities and colleges
General subdivision Disertations
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Theses
Holdings
Withdrawn status Lost status Source of classification or shelving scheme Damaged status Not for loan Home library Current library Date acquired Total checkouts Full call number Barcode Date last seen Copy number Price effective from Koha item type
  Not lost Library of Congress Classification   Not for loan UMPLIB GAMBANG UMPLIB GAMBANG 04/09/2019   FKKSA .I45 2018 r Thesis 0000125090 04/09/2019 1 04/09/2019 Thesis
  Not lost Library of Congress Classification   Not for loan UMPLIB GAMBANG UMPLIB GAMBANG 04/09/2019   CD 11633 | FKKSA .I45 2018 r Thesis 0000125091 04/09/2019 1 04/09/2019 Thesis

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