MARC details
| 000 -LEADER |
|---|
| fixed length control field |
02847ntm a2200325 i 4500 |
| 003 - CONTROL NUMBER IDENTIFIER |
|---|
| control field |
MY-KuUP |
| 005 - DATE AND TIME OF LATEST TRANSACTION |
|---|
| control field |
20260921141153.0 |
| 006 - FIXED-LENGTH DATA ELEMENTS--ADDITIONAL MATERIAL CHARACTERISTICS |
|---|
| fixed length control field |
t||||fr|||| 000 0 |
| 007 - PHYSICAL DESCRIPTION FIXED FIELD--GENERAL INFORMATION |
|---|
| fixed length control field |
ta |
| 008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION |
|---|
| fixed length control field |
131031t20132013my da f abm 000 0 eng d |
| 020 ## - INTERNATIONAL STANDARD BOOK NUMBER |
|---|
| International Standard Book Number |
THE0007995(Local) |
| Qualifying information |
hardback |
| 040 ## - CATALOGING SOURCE |
|---|
| Original cataloging agency |
UMP |
| Language of cataloging |
eng |
| Transcribing agency |
UMP |
| Description conventions |
rda |
| 090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN) |
|---|
| Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) |
QD281.D4 C49 2013 rs Bc. |
| 100 1# - MAIN ENTRY--PERSONAL NAME |
|---|
| Personal name |
Chye, Joanna Jo Ean, |
| Relator term |
author. |
| 245 #0 - TITLE STATEMENT |
|---|
| Title |
Physicochemical characterization and carbon gasification analysis of used propane dehydrogenation catalyst / |
| Statement of responsibility, etc. |
Joanna Chye Jo Ean |
| 264 #1 - PRODUCTION, PUBLICATION, DISTRIBUTION, MANUFACTURE, AND COPYRIGHT NOTICE |
|---|
| Place of production, publication, distribution, manufacture |
Kuantan, Pahang : |
| Name of producer, publisher, distributor, manufacturer |
UMP, |
| Date of production, publication, distribution, manufacture, or copyright notice |
2013 |
| 264 #4 - PRODUCTION, PUBLICATION, DISTRIBUTION, MANUFACTURE, AND COPYRIGHT NOTICE |
|---|
| Date of production, publication, distribution, manufacture, or copyright notice |
©2013 |
| 300 ## - PHYSICAL DESCRIPTION |
|---|
| Extent |
xvii, 91 pages : |
| Other physical details |
illustrations ; |
| Dimensions |
30 cm. + |
| Accompanying material |
1 CD-ROM |
| 336 ## - CONTENT TYPE |
|---|
| Source |
rdacontent |
| Content type term |
text |
| 337 ## - MEDIA TYPE |
|---|
| Source |
rdamedia |
| Media type term |
unmediated |
| 338 ## - CARRIER TYPE |
|---|
| Source |
rdacarrier |
| Carrier type term |
volume |
| 502 ## - DISSERTATION NOTE |
|---|
| Dissertation note |
Project paper (Bachelor of Chemical Engineering) -- Universiti Malaysia Pahang – 2013 |
| 504 ## - BIBLIOGRAPHY, ETC. NOTE |
|---|
| Bibliography, etc. note |
Bibliography : p. 79-84 |
| 520 3# - SUMMARY, ETC. |
|---|
| Summary, etc. |
Propylene is widely used in industry as a starting material for many downstream petrochemical productions in particular polypropylene. It is produced by catalytic dehydrogenation process near atmospheric pressure and 580-650 °C over Pt-Sn/Al2O3 catalyst. However, there are also many undesired reactions occur notably formation of carbon due to high temperature hydrocarbon decomposition. Physicochemical characters including element quantity and quality, nature, morphology, structure and location of coke deposited on used Pt-Sn/Al2O3 catalyst were studied by several characterization techniques i.e. Liquid Nitrogen Physisorption, X-ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR), X-ray Photoelectron Spectroscopy (XPS), Field Emission Scanning Electron Microscope (FESEM) and Thermogravimetric Analysis (TGA). XPS analysis detected the constituents of the catalyst and also other elements i.e. K, S, Cl and Fe. FTIR identified the presents of various hydrocarbon species particularly dehydrogenated species; olefins and aromatics while crystallite pre-graphite which indicates the coke was detected by XRD. FESEM images also proved the presents of coke in amorphous, whiskers-like form. BET surface for coked catalyst was only 78.943 m2 g-1. The coke formed was altered by Sn promoter towards the bulk alumina support as discovered by TGA. Subsequently, for carbon removal analysis, the highest gasification obtained as oxygen and followed by air. Nitrogen gasified coke with the lowest rate and the activation energy for nitrogen is higher than oxygen and air. Air is suitable gasifying agent as it can removed carbon content like oxygen but in a mild condition with lower heat released. Different heating ramps did not affect the gasification mechanism. |
| 650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM |
|---|
| Topical term or geographic name entry element |
Coal gasification |
| 650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM |
|---|
| Topical term or geographic name entry element |
Polypropylene |
| 650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM |
|---|
| Topical term or geographic name entry element |
Dehydrogenation |
| 650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM |
|---|
| Topical term or geographic name entry element |
Catalysis |
| 942 ## - ADDED ENTRY ELEMENTS (KOHA) |
|---|
| Source of classification or shelving scheme |
Library of Congress Classification |
| Koha item type |
Final Year Report |