Experimental measurement and prediction of thermophysical properties of methyl tert-butyl ether (MTBE) with methanol, diisopropyl ether (DIPE) and N-methylaniline binary mixtures / (Record no. 94204)

MARC details
000 -LEADER
fixed length control field 04204ntm a2200373 i 4500
003 - CONTROL NUMBER IDENTIFIER
control field MY-KuUP
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20251125105727.0
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007 - PHYSICAL DESCRIPTION FIXED FIELD--GENERAL INFORMATION
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fixed length control field 201012t20192019m a|||fram|| 000 0 eng d
020 ## - INTERNATIONAL STANDARD BOOK NUMBER
International Standard Book Number THE0008800(Local)
Qualifying information hardback
040 ## - CATALOGING SOURCE
Original cataloging agency UMP
Language of cataloging eng
Transcribing agency UMP
Description conventions rda
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) FKKSA .A45 2019 r Thesis
100 1# - MAIN ENTRY--PERSONAL NAME
Personal name Ali, Mohammed Rashid,
Relator term author.
245 10 - TITLE STATEMENT
Title Experimental measurement and prediction of thermophysical properties of methyl tert-butyl ether (MTBE) with methanol, diisopropyl ether (DIPE) and N-methylaniline binary mixtures /
Statement of responsibility, etc. Mohammed Rashid Ali
264 #1 - PRODUCTION, PUBLICATION, DISTRIBUTION, MANUFACTURE, AND COPYRIGHT NOTICE
Place of production, publication, distribution, manufacture Kuantan, Pahang :
Name of producer, publisher, distributor, manufacturer UMP,
Date of production, publication, distribution, manufacture, or copyright notice 2019
264 #4 - PRODUCTION, PUBLICATION, DISTRIBUTION, MANUFACTURE, AND COPYRIGHT NOTICE
Date of production, publication, distribution, manufacture, or copyright notice © 2019
300 ## - PHYSICAL DESCRIPTION
Extent xiv, 121 pages :
Other physical details illustrations (some color) ;
Dimensions 30 cm. +
Accompanying material 1 CD-ROM
336 ## - CONTENT TYPE
Content type term text
Source rdacontent
336 ## - CONTENT TYPE
Content type term 1 CD-ROM
Source rdacontent
337 ## - MEDIA TYPE
Media type term unmediated
Source rdamedia
337 ## - MEDIA TYPE
Media type term computer
Source rdamedia
338 ## - CARRIER TYPE
Carrier type term volume
Source rdacarrier
338 ## - CARRIER TYPE
Carrier type term computer disc
Source rdacarrier
347 ## - DIGITAL FILE CHARACTERISTICS
File type text file
Encoding format PDF
Source rda
500 ## - GENERAL NOTE
General note Faculty of Chemical and Natural Resources Engineering
502 ## - DISSERTATION NOTE
Dissertation note Thesis (Master of Science) -- Universiti Malaysia Pahang – 2019
504 ## - BIBLIOGRAPHY, ETC. NOTE
Bibliography, etc. note Includes bibliographical references
520 3# - SUMMARY, ETC.
Summary, etc. Thermophysical properties of hydrocarbon mixtures play a vital role in process industries such as distillation, extraction operations, material and energy balance as well as solving problems in heat transfer, mass transfer, and fluid flow. Studies on thermophysical properties such as density and viscosity of liquid mixtures within a wide range of composition and temperatures are valuable sources of information for examining the relationship between the internal structure of the system and its physical properties. In this work density and viscosity of methyl tert-butyl ether (MTBE) with methanol, diisopropyl ether (DIPE) and N-methylaniline (NMA) binary liquid mixtures have been measured by using DMA 4500 M density meter and Anton Paar´s Stabinger Viscometer™ SVM™ 3000 at temperatures of 35 °C, 40 °C and 45 °C. The densities and viscosities of MTBE-methanol and MTBE-NMA binary mixtures show decreasing trends with the increase of MTBE composition at all temperature. On the contrary, binary mixture of MTBE-DIPE shows an increment in density and viscosity under the same condition. In addition, Jouyban-Acree equation has been used to predict density and viscosity where low mean absolute error (MAE) of 0.3 % and 2.2 % have been obtained. The excess molar volumes and viscosity deviation have been calculated using the density and viscosity experimental data and correlated with Redlich-Kister equation where a good fitted has been obtained. Sigmoid shapes of excess molar volumes have been obtained for all binary mixture. It has been found that in order to obtain a strong combination fuel, negative excess molar volumes are preferable. Thus binary mixtures of MTBE-methanol and MTBE-NMA must be mixed at high mole fraction of MTBE. However low mole fraction of MTBE must be used in the case of MTBE-DIPE binary mixture. The viscosity deviations of all binary mixtures are negative and were observed to decrease with an increase of temperatures. This indicates the strength of chemical or specific interaction for binary mixtures such as hydrogen binding between dissimilar molecules. Further investigation of molecular interaction has been performed using Attenuated Total Reflectance-Fourier Transform Infrared (ATR-FTIR) and Proton Nuclear Magnetic Resonance (1H-NMR) spectroscopy analysis using ratios 3:7 and 7:3 of binary mixture. It has been observed that intermolecular interaction is more evident for ratio 7:3 for MTBE-methanol and MTBE-NMA. However, the variation in percentage composition of MTBE with DIPE of the individual components does not seem to affect significantly the spectrum of the binary mixture. Hence, this suggests that the intermolecular interaction between MTBE and DIPE is less dependent on the amount of DIPE present in the binary mixture.
610 20 - SUBJECT ADDED ENTRY--CORPORATE NAME
Corporate name or jurisdiction name as entry element Faculty of Chemical and Natural Resources Engineering
General subdivision Dissertations
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Universities and colleges
General subdivision Disertations
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Theses
942 ## - ADDED ENTRY ELEMENTS (KOHA)
Source of classification or shelving scheme Library of Congress Classification
Koha item type Thesis
Holdings
Withdrawn status Lost status Source of classification or shelving scheme Damaged status Not for loan Collection Home library Current library Date acquired Total checkouts Full call number Barcode Date last seen Copy number Price effective from Koha item type
  Not lost Library of Congress Classification   Not for loan Reference UMPLIB GAMBANG UMPLIB GAMBANG 12/10/2020   FKKSA .A45 2019 r Thesis T000000918 15/03/2021 1 12/10/2020 Thesis
  Not lost Library of Congress Classification     Reference UMPLIB GAMBANG UMPLIB GAMBANG 12/10/2020   CD12686 T000000919 06/12/2021 1 12/10/2020 Thesis

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