Photocatalytic degradation of pome over lanthanum doped calcium oxide derived from cockle shells / (Record no. 95429)

MARC details
000 -LEADER
fixed length control field 04189ntm a2200361 i 4500
003 - CONTROL NUMBER IDENTIFIER
control field MY-KuUP
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20251125105846.0
006 - FIXED-LENGTH DATA ELEMENTS--ADDITIONAL MATERIAL CHARACTERISTICS
fixed length control field t||||fr|||| 000 0
008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION
fixed length control field 220303s2020 my a|||fr|||| 000 0 eng d
020 ## - INTERNATIONAL STANDARD BOOK NUMBER
International Standard Book Number THE0009128(Local)
Qualifying information hardback
040 ## - CATALOGING SOURCE
Original cataloging agency UMP
Language of cataloging eng
Transcribing agency UMP
Description conventions rda
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) FTKKP .S53 2020 r Thesis
100 1# - MAIN ENTRY--PERSONAL NAME
Personal name Siti Shariah Ghazali,
Relator term author.
245 10 - TITLE STATEMENT
Title Photocatalytic degradation of pome over lanthanum doped calcium oxide derived from cockle shells /
Statement of responsibility, etc. Siti Shariah Ghazali
264 #1 - PRODUCTION, PUBLICATION, DISTRIBUTION, MANUFACTURE, AND COPYRIGHT NOTICE
Place of production, publication, distribution, manufacture Kuantan, Pahang :
Name of producer, publisher, distributor, manufacturer UMP,
Date of production, publication, distribution, manufacture, or copyright notice 2020
264 #4 - PRODUCTION, PUBLICATION, DISTRIBUTION, MANUFACTURE, AND COPYRIGHT NOTICE
Date of production, publication, distribution, manufacture, or copyright notice © 2020
300 ## - PHYSICAL DESCRIPTION
Extent xiii, 116 pages :
Other physical details illustrations (some color) ;
Dimensions 30 cm. +
Accompanying material 1 CD-ROM
336 ## - CONTENT TYPE
Content type term text
Source rdacontent
336 ## - CONTENT TYPE
Content type term text
Source rdacontent
337 ## - MEDIA TYPE
Media type term unmediated
Source rdamedia
337 ## - MEDIA TYPE
Media type term computer
Source rdamedia
338 ## - CARRIER TYPE
Carrier type term volume
Source rdacarrier
338 ## - CARRIER TYPE
Carrier type term computer disc
Source rdacarrier
347 ## - DIGITAL FILE CHARACTERISTICS
File type text file
Encoding format PDF
Source rda
500 ## - GENERAL NOTE
General note Faculty of Chemical and Process Engineering Technology
502 ## - DISSERTATION NOTE
Dissertation note Thesis (Master of Science) -- Universiti Malaysia Pahang – 2020
504 ## - BIBLIOGRAPHY, ETC. NOTE
Bibliography, etc. note Includes bibliographical references
520 3# - SUMMARY, ETC.
Summary, etc. Palm Oil Mill Effluent (POME) is one of the main problems faces by oil palm industry in Malaysia due to its high chemical oxygen demand (COD) and biochemical oxygen demand (BOD). Recently, photocatalysFis has been used in several studies to treat wastewater due to its ability to mineralize the organic compounds. However, the common photocatalysts used in treating POME such as titanium oxide (TiO2) and zinc oxide (ZnO) consist of metals that have limited availability. On the other hand, cockle shells have been dumped and left untreated to the environment. As one possible solution to address both environmental problems, this study utilized cockle shell as renewable feedstock of calcium carbonate which was converted to calcium oxide (CaO) that was used as photocatalyst to treat POME. Therefore, the aim of this study is to investigate the ability of cockle shell waste to be transformed to CaO to act as photocatalyst in the treatment of POME via photocatalysis reaction. Lanthanum (La) was used in this study to act as dopant to enhance the photocatalytic activity of CaO. The CaO used in this study was converted from cockle shell wastes through calcination process at 900◦C where later the sample was denoted as Ca900. Ca900 was doped with 1 wt%, 3 wt% and 5 wt% of La using wet impregnation method where the doped photocatalyst were denoted as LaCa. Then, the photocatalysts were tested on POME under UV light in batch system by varying the effect of several operational parameters such as stirring speed, photocatalyst loadings, La loadings and oxidizing agent. All fresh and spent photocatalysts powder were characterized using fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), brunauer-emmett-teller (BET), scanning electron microsopy (SEM), energy dispersion X-ray analyser (EDX), thermogravimetric analysis (TGA), inductively coupled plasma mass spectrometry (ICP-MS) and UV-Vis diffuse reflectance spectra. The results obtained from this study show that it is achievable to produce CaO from cockle shell that can be used in photocatalytic degradation of POME. Through this research, it was found that 3 wt% of LaCa with 3.0 g/L of photocatalyst loadings at 300 rpm has highest photocatalytic activity with 54% removal compared to others. However, the removal efficiency of POME increases when oxygen as oxidizing agent were used which is 66% rather than during limited oxygen condition (54%). The kinetic data of POME degradation were fitted Langmuir-Hinshelwood kinetic model as first order reaction. In conclusion, the findings of this study imply that the contaminants in POME can be greatly reduced by utilizing La doped CaO which CaO derived from cockle shell waste.
610 20 - SUBJECT ADDED ENTRY--CORPORATE NAME
Corporate name or jurisdiction name as entry element Faculty of Chemical and Process Engineering Technology
General subdivision Dissertations
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Universities and colleges
General subdivision Dissertations
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Theses
942 ## - ADDED ENTRY ELEMENTS (KOHA)
Source of classification or shelving scheme Library of Congress Classification
Koha item type Thesis
Holdings
Withdrawn status Lost status Source of classification or shelving scheme Damaged status Not for loan Collection Home library Current library Shelving location Date acquired Total checkouts Full call number Barcode Date last seen Copy number Price effective from Koha item type
  Not lost Library of Congress Classification   Not for loan Reference UMPLIB GAMBANG UMPLIB GAMBANG Reference 28/01/2021   FTKKP .S53 2020 r Thesis T000001347 26/04/2022 1 28/01/2021 Thesis
  Not lost Library of Congress Classification   Not for loan Reference UMPLIB GAMBANG UMPLIB GAMBANG   03/03/2022   CD12840 T000001348 30/01/2023 1 03/03/2022 Thesis

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