MARC details
| 000 -LEADER |
| fixed length control field |
03995ntm a2200373 i 4500 |
| 003 - CONTROL NUMBER IDENTIFIER |
| control field |
MY-KuUP |
| 005 - DATE AND TIME OF LATEST TRANSACTION |
| control field |
20251125110732.0 |
| 006 - FIXED-LENGTH DATA ELEMENTS--ADDITIONAL MATERIAL CHARACTERISTICS |
| fixed length control field |
t||||fr|||| 000 0 |
| 007 - PHYSICAL DESCRIPTION FIXED FIELD--GENERAL INFORMATION |
| fixed length control field |
ta |
| 008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION |
| fixed length control field |
230427t20232023my a|||fr|||| 000 0 eng d |
| 020 ## - INTERNATIONAL STANDARD BOOK NUMBER |
| International Standard Book Number |
THE0009639 (Local) |
| Qualifying information |
Hardback |
| 040 ## - CATALOGING SOURCE |
| Original cataloging agency |
UMP |
| Language of cataloging |
eng |
| Transcribing agency |
UMP |
| Description conventions |
rda |
| 090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN) |
| Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) |
FIST .L44 2023 r Thesis |
| 100 1# - MAIN ENTRY--PERSONAL NAME |
| Personal name |
Lee Soon Poh, |
| Relator term |
author. |
| 245 10 - TITLE STATEMENT |
| Title |
Phenothiazine functionalized reduced graphene oxide aerogel for adsorption and charge storage / |
| Statement of responsibility, etc. |
Lee Soon Poh |
| 264 #1 - PRODUCTION, PUBLICATION, DISTRIBUTION, MANUFACTURE, AND COPYRIGHT NOTICE |
| Place of production, publication, distribution, manufacture |
Kuantan, Pahang : |
| Name of producer, publisher, distributor, manufacturer |
UMP, |
| Date of production, publication, distribution, manufacture, or copyright notice |
2023 |
| 264 #4 - PRODUCTION, PUBLICATION, DISTRIBUTION, MANUFACTURE, AND COPYRIGHT NOTICE |
| Date of production, publication, distribution, manufacture, or copyright notice |
©2023 |
| 300 ## - PHYSICAL DESCRIPTION |
| Extent |
xix, 176 pages : |
| Other physical details |
illustration (some colour) ; |
| Dimensions |
30 cm. + |
| Accompanying material |
1 CD-ROM |
| 336 ## - CONTENT TYPE |
| Source |
rdacontent |
| Content type term |
text |
| 336 ## - CONTENT TYPE |
| Source |
rdacontent |
| Content type term |
text |
| 337 ## - MEDIA TYPE |
| Source |
rdamedia |
| Media type term |
unmediated |
| 337 ## - MEDIA TYPE |
| Source |
rdamedia |
| Media type term |
computer |
| 338 ## - CARRIER TYPE |
| Source |
rdacarrier |
| Carrier type term |
volume |
| 338 ## - CARRIER TYPE |
| Source |
rdacarrier |
| Carrier type term |
computer disc |
| 347 ## - DIGITAL FILE CHARACTERISTICS |
| Source |
rda |
| File type |
text file |
| Encoding format |
PDF |
| 500 ## - GENERAL NOTE |
| General note |
Faculty of Industrial Science and Technology |
| 502 ## - DISSERTATION NOTE |
| Dissertation note |
Thesis (Doctor of Philosophy (Biotechnology)) -- Universiti Malaysia Pahang – 2023 |
| 504 ## - BIBLIOGRAPHY, ETC. NOTE |
| Bibliography, etc. note |
Bibliography : p. 134-159 |
| 520 3# - SUMMARY, ETC. |
| Summary, etc. |
The development of recent technology escalates the massive demand for charge storage devices in maintaining the function of electronic devices and industrial machines. Such a scenario increases industrial operations and indirectly increases water pollution issues. Reduced graphene oxide (rGO) is an emerging carbon material discovered to be the potential material that can overcome the limitations of activated carbon in adsorption and charge storage. Performance enhancement on both applications via rGO functionalization often involved a complex synthesis approach or relatively high-cost process. In this study, the different graphene oxide (GO) sheet size precursors were obtained via sonication and the physicochemical properties of the rGO xerogel upon reduction were examined. The one-step functionalized phenothiazine-rGO (PTZ-rGO) aerogel was synthesis via photoreduction using PTZ as a reductant and functionalization precursor. The optimized sheet size precursor (4h GO) renders excellent pore strength through optimal parallel sheet stacking that prevents pore deformation during xerogel formation. Such an effect allows the 4h rGO to have a high surface area (190.40 m2 g−1) and pore volume (0.261 cm3 g−1). The functionalized PTZ-rGO aerogel reflects the important role of PTZ in preventing restacking of rGO layers and thus, generates a high surface area (539.67 m2 g−1) material. The synergistic effect of high porosity and excellent surface properties of rGO xerogel and PTZ-rGO aerogel structured them to be well-performed in electrochemical analysis. The optimal remaining oxygen in rGO xerogel and optimal PTZ loaded on PTZ-rGO aerogel contribute to the diffusive charge storage mechanism allowing it to obtain 182 F g−1 and 193.4 F g−1 at 0.75 A g−1 for 4h rGO and P8G1 sample, respectively. The excellent physicochemical properties of 4h rGO and P8G1 also build up a high-performing adsorbent for organic and heavy metal ions removal. The adsorption kinetic obeys the pseudo-second-order kinetic model, which indicates chemisorption as a pollutant removal mechanism for entire rGO xerogel and PTZ-rGO aerogel samples. Langmuir adsorption isotherms well describe the adsorption behavior of rGO xerogel and PTZ-rGO aerogel for all the adsorbates except Fe3+ which fits better in Freundlich isotherm. Hence, the extraordinary performance of the optimized PTZ-rGO aerogel in electrochemical and pollutant removal renders it a suitable candidate to be implemented as a supercapacitor electrode material and excellent adsorbent material. Therefore, PTZ-rGO aerogel contributes to the solution for increasing charge storage demand and wastewater remediation. |
| 610 20 - SUBJECT ADDED ENTRY--CORPORATE NAME |
| Corporate name or jurisdiction name as entry element |
Faculty of Industrial Science & Technology |
| General subdivision |
Dissertations |
| 650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM |
| Topical term or geographic name entry element |
Universities and colleges |
| General subdivision |
Dissertations |
| 650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM |
| Topical term or geographic name entry element |
Theses |
| General subdivision |
Dissertations |
| 942 ## - ADDED ENTRY ELEMENTS (KOHA) |
| Source of classification or shelving scheme |
Library of Congress Classification |
| Koha item type |
Thesis |