Phenothiazine functionalized reduced graphene oxide aerogel for adsorption and charge storage / (Record no. 99417)

MARC details
000 -LEADER
fixed length control field 03995ntm a2200373 i 4500
003 - CONTROL NUMBER IDENTIFIER
control field MY-KuUP
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20251125110732.0
006 - FIXED-LENGTH DATA ELEMENTS--ADDITIONAL MATERIAL CHARACTERISTICS
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007 - PHYSICAL DESCRIPTION FIXED FIELD--GENERAL INFORMATION
fixed length control field ta
008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION
fixed length control field 230427t20232023my a|||fr|||| 000 0 eng d
020 ## - INTERNATIONAL STANDARD BOOK NUMBER
International Standard Book Number THE0009639 (Local)
Qualifying information Hardback
040 ## - CATALOGING SOURCE
Original cataloging agency UMP
Language of cataloging eng
Transcribing agency UMP
Description conventions rda
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) FIST .L44 2023 r Thesis
100 1# - MAIN ENTRY--PERSONAL NAME
Personal name Lee Soon Poh,
Relator term author.
245 10 - TITLE STATEMENT
Title Phenothiazine functionalized reduced graphene oxide aerogel for adsorption and charge storage /
Statement of responsibility, etc. Lee Soon Poh
264 #1 - PRODUCTION, PUBLICATION, DISTRIBUTION, MANUFACTURE, AND COPYRIGHT NOTICE
Place of production, publication, distribution, manufacture Kuantan, Pahang :
Name of producer, publisher, distributor, manufacturer UMP,
Date of production, publication, distribution, manufacture, or copyright notice 2023
264 #4 - PRODUCTION, PUBLICATION, DISTRIBUTION, MANUFACTURE, AND COPYRIGHT NOTICE
Date of production, publication, distribution, manufacture, or copyright notice ©2023
300 ## - PHYSICAL DESCRIPTION
Extent xix, 176 pages :
Other physical details illustration (some colour) ;
Dimensions 30 cm. +
Accompanying material 1 CD-ROM
336 ## - CONTENT TYPE
Source rdacontent
Content type term text
336 ## - CONTENT TYPE
Source rdacontent
Content type term text
337 ## - MEDIA TYPE
Source rdamedia
Media type term unmediated
337 ## - MEDIA TYPE
Source rdamedia
Media type term computer
338 ## - CARRIER TYPE
Source rdacarrier
Carrier type term volume
338 ## - CARRIER TYPE
Source rdacarrier
Carrier type term computer disc
347 ## - DIGITAL FILE CHARACTERISTICS
Source rda
File type text file
Encoding format PDF
500 ## - GENERAL NOTE
General note Faculty of Industrial Science and Technology
502 ## - DISSERTATION NOTE
Dissertation note Thesis (Doctor of Philosophy (Biotechnology)) -- Universiti Malaysia Pahang – 2023
504 ## - BIBLIOGRAPHY, ETC. NOTE
Bibliography, etc. note Bibliography : p. 134-159
520 3# - SUMMARY, ETC.
Summary, etc. The development of recent technology escalates the massive demand for charge storage devices in maintaining the function of electronic devices and industrial machines. Such a scenario increases industrial operations and indirectly increases water pollution issues. Reduced graphene oxide (rGO) is an emerging carbon material discovered to be the potential material that can overcome the limitations of activated carbon in adsorption and charge storage. Performance enhancement on both applications via rGO functionalization often involved a complex synthesis approach or relatively high-cost process. In this study, the different graphene oxide (GO) sheet size precursors were obtained via sonication and the physicochemical properties of the rGO xerogel upon reduction were examined. The one-step functionalized phenothiazine-rGO (PTZ-rGO) aerogel was synthesis via photoreduction using PTZ as a reductant and functionalization precursor. The optimized sheet size precursor (4h GO) renders excellent pore strength through optimal parallel sheet stacking that prevents pore deformation during xerogel formation. Such an effect allows the 4h rGO to have a high surface area (190.40 m2 g−1) and pore volume (0.261 cm3 g−1). The functionalized PTZ-rGO aerogel reflects the important role of PTZ in preventing restacking of rGO layers and thus, generates a high surface area (539.67 m2 g−1) material. The synergistic effect of high porosity and excellent surface properties of rGO xerogel and PTZ-rGO aerogel structured them to be well-performed in electrochemical analysis. The optimal remaining oxygen in rGO xerogel and optimal PTZ loaded on PTZ-rGO aerogel contribute to the diffusive charge storage mechanism allowing it to obtain 182 F g−1 and 193.4 F g−1 at 0.75 A g−1 for 4h rGO and P8G1 sample, respectively. The excellent physicochemical properties of 4h rGO and P8G1 also build up a high-performing adsorbent for organic and heavy metal ions removal. The adsorption kinetic obeys the pseudo-second-order kinetic model, which indicates chemisorption as a pollutant removal mechanism for entire rGO xerogel and PTZ-rGO aerogel samples. Langmuir adsorption isotherms well describe the adsorption behavior of rGO xerogel and PTZ-rGO aerogel for all the adsorbates except Fe3+ which fits better in Freundlich isotherm. Hence, the extraordinary performance of the optimized PTZ-rGO aerogel in electrochemical and pollutant removal renders it a suitable candidate to be implemented as a supercapacitor electrode material and excellent adsorbent material. Therefore, PTZ-rGO aerogel contributes to the solution for increasing charge storage demand and wastewater remediation.
610 20 - SUBJECT ADDED ENTRY--CORPORATE NAME
Corporate name or jurisdiction name as entry element Faculty of Industrial Science & Technology
General subdivision Dissertations
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Universities and colleges
General subdivision Dissertations
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Theses
General subdivision Dissertations
942 ## - ADDED ENTRY ELEMENTS (KOHA)
Source of classification or shelving scheme Library of Congress Classification
Koha item type Thesis
Holdings
Withdrawn status Lost status Source of classification or shelving scheme Damaged status Not for loan Collection Home library Current library Date acquired Total checkouts Full call number Barcode Date last seen Copy number Price effective from Koha item type
  Not lost Library of Congress Classification   Not for loan Reference UMPLIB GAMBANG UMPLIB GAMBANG 27/04/2023   FIST .L44 2023 r Thesis T000002310 27/04/2023 1 27/04/2023 Thesis
  Not lost Library of Congress Classification   In Transit   UMPLIB GAMBANG UMPLIB GAMBANG 27/04/2023   CD13322 T000002311 27/04/2023 1 27/04/2023 Thesis

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