Study on the ionic conduction properties of alginate-poly (vinyl alcohol) doped ammonium nitrate based bio-polymer blend electrolytes / (Record no. 99508)

MARC details
000 -LEADER
fixed length control field 03932ntm a2200373 i 4500
003 - CONTROL NUMBER IDENTIFIER
control field MY-KuUP
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20251125110738.0
006 - FIXED-LENGTH DATA ELEMENTS--ADDITIONAL MATERIAL CHARACTERISTICS
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007 - PHYSICAL DESCRIPTION FIXED FIELD--GENERAL INFORMATION
fixed length control field ta
008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION
fixed length control field 230509t20232023my a|||fr|||| 000 0 eng d
020 ## - INTERNATIONAL STANDARD BOOK NUMBER
International Standard Book Number THE0009653 (Local)
Qualifying information Hardback
040 ## - CATALOGING SOURCE
Original cataloging agency UMP
Language of cataloging eng
Transcribing agency UMP
Description conventions rda
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) FIST .A95 2023 r Thesis
100 1# - MAIN ENTRY--PERSONAL NAME
Personal name Nuraziliana Binti Muhd Ghazali,
Relator term author.
245 10 - TITLE STATEMENT
Title Study on the ionic conduction properties of alginate-poly (vinyl alcohol) doped ammonium nitrate based bio-polymer blend electrolytes /
Remainder of title
Statement of responsibility, etc. Nuraziliana Binti Muhd Ghazali
264 #1 - PRODUCTION, PUBLICATION, DISTRIBUTION, MANUFACTURE, AND COPYRIGHT NOTICE
Place of production, publication, distribution, manufacture Kuantan, Pahang :
Name of producer, publisher, distributor, manufacturer UMP,
Date of production, publication, distribution, manufacture, or copyright notice 2023
264 #4 - PRODUCTION, PUBLICATION, DISTRIBUTION, MANUFACTURE, AND COPYRIGHT NOTICE
Date of production, publication, distribution, manufacture, or copyright notice ©2023
300 ## - PHYSICAL DESCRIPTION
Extent xvii, 103 pages :
Other physical details illustrations (some color) ;
Dimensions 30 cm. +
Accompanying material 1 CD-ROM
336 ## - CONTENT TYPE
Source rdacontent
Content type term text
336 ## - CONTENT TYPE
Source rdacontent
Content type term text
337 ## - MEDIA TYPE
Source rdamedia
Media type term unmediated
337 ## - MEDIA TYPE
Source rdamedia
Media type term computer
338 ## - CARRIER TYPE
Source rdacarrier
Carrier type term volume
338 ## - CARRIER TYPE
Source rdacarrier
Carrier type term computer disc
347 ## - DIGITAL FILE CHARACTERISTICS
Source rda
File type text file
Encoding format PDF
500 ## - GENERAL NOTE
General note Faculty of Industrial Sciences and Technology
502 ## - DISSERTATION NOTE
Dissertation note Thesis (Master of Science) -- Universiti Malaysia Pahang – 2023
504 ## - BIBLIOGRAPHY, ETC. NOTE
Bibliography, etc. note Includes bibliographical references
520 3# - SUMMARY, ETC.
Summary, etc. The utilization of biomaterial in the production of polymer electrolytes, particularly in electrochemical devices, is currently receiving a great deal of attention. This is because these bio-polymer-based electrolytes have the potential to alleviate the environmental issues, disposal of waste, and human-health concerns through the usage of non-hazardous materials in the energy device system. The aim of this research is to create and characterize a bio-polymer blend electrolyte (BBEs) system made from alginate blended with poly (vinyl alcohol) (PVA) as the bio-polymer host and doped with different contents of ammonium nitrate (NH4NO3) ionic salt. The BBEs system was developed using the solution casting method, and the resulting films showed a transparent, freestanding, and flexible appearance. Fourier transform infrared (FTIR) spectroscopy was used to confirm the complexation occurs in the BBEs. X-ray diffraction (XRD) analysis and scanning electron microscopy (SEM) were used to reveal the amorphous nature and morphology of the BBEs. The results of the thermogravimetric analysis (TGA) showed that the thermal stability of the BBEs has been enhanced as a result of the addition of NH4NO3. Electrical impedance spectroscopy (EIS) was used to measure the ionic conductivity of the BBEs system, where the highest ionic conductivity was revealed to be 5.20 × 10-4 S cm-1 when 35 wt.% of NH4NO3 was added into the system. The increase of ionic conductivity at room temperature was due to the enhanced amorphous nature as well as complexation between the lone pair oxygen at the Alg-PVA bio-polymer chain backbone and H+ from NH4NO3. The effect of temperature on the ionic conductivity of BBEs revealed that all BBEs obeyed Arrhenius behavior and displayed a lower activation energy, Ea of 0.10 eV for the highest conducting BBEs. Based on the dielectric response analysis, it was revealed that the ionic mobility, μ, number density of charge carriers, η, and diffusion coefficient, D of the H+ were all factors that influenced the ionic conductivity of the BBEs. Through the use of transference number measurement (TNM) analysis, the BBEs with the greatest ionic conductivity was analyzed to determine the ion dominancy. The tion was found to be 0.51, and this finding verified the predominance of H+ in the present BBEs system. Based on these results, this BBEs system has a high potential to be utilized in electrochemical device applications as an electrolyte, specifically in electrical double layer capacitors and proton batteries.
610 20 - SUBJECT ADDED ENTRY--CORPORATE NAME
Corporate name or jurisdiction name as entry element Faculty of Industrial Sciences and Technology
General subdivision Dissertations
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Universities and colleges
General subdivision Dissertations
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Theses
General subdivision Dissertations
942 ## - ADDED ENTRY ELEMENTS (KOHA)
Source of classification or shelving scheme Library of Congress Classification
Koha item type Thesis
Holdings
Withdrawn status Lost status Source of classification or shelving scheme Damaged status Not for loan Collection Home library Current library Date acquired Total checkouts Full call number Barcode Date last seen Price effective from Koha item type
  Not lost Library of Congress Classification   Not for loan Reference UMPLIB GAMBANG UMPLIB GAMBANG 09/05/2023   FIST .A95 2023 r Thesis T000002365 09/05/2023 09/05/2023 Thesis
  Not lost Library of Congress Classification   In Transit   UMPLIB GAMBANG UMPLIB GAMBANG 09/05/2023   CD13348 T000002366 09/05/2023 09/05/2023 Thesis

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