Enhancing anaerobic digestion of palm oil mill effluent (POME) by addition of cao derived from waste cockle shell as a buffering solution in an upflow anaerobic sludge blanket (UASB) reactor / (Record no. 99920)

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fixed length control field 05811ntm a2200373 i 4500
003 - CONTROL NUMBER IDENTIFIER
control field MY-KuUP
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20251125110804.0
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007 - PHYSICAL DESCRIPTION FIXED FIELD--GENERAL INFORMATION
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020 ## - INTERNATIONAL STANDARD BOOK NUMBER
International Standard Book Number THE0009695 (Local)
Qualifying information Hardback
040 ## - CATALOGING SOURCE
Original cataloging agency UMP
Language of cataloging eng
Transcribing agency UMP
Description conventions rda
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) FTKKP .M65 2023 r Thesis
100 1# - MAIN ENTRY--PERSONAL NAME
Personal name Mohamad Mokhtar Bin Ibrahim,
Relator term author.
245 10 - TITLE STATEMENT
Title Enhancing anaerobic digestion of palm oil mill effluent (POME) by addition of cao derived from waste cockle shell as a buffering solution in an upflow anaerobic sludge blanket (UASB) reactor /
Statement of responsibility, etc. Mohamad Mokhtar Bin Ibrahim
264 #1 - PRODUCTION, PUBLICATION, DISTRIBUTION, MANUFACTURE, AND COPYRIGHT NOTICE
Place of production, publication, distribution, manufacture Pahang :
Name of producer, publisher, distributor, manufacturer UMP,
Date of production, publication, distribution, manufacture, or copyright notice 2023
264 #4 - PRODUCTION, PUBLICATION, DISTRIBUTION, MANUFACTURE, AND COPYRIGHT NOTICE
Date of production, publication, distribution, manufacture, or copyright notice ©2023
300 ## - PHYSICAL DESCRIPTION
Extent xv, 175 pages :
Other physical details Illustration ;
Dimensions 30 cm.+
Accompanying material 1-CD ROM
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Source rdacontent
Content type term text
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Source rdacontent
Content type term text
337 ## - MEDIA TYPE
Source rdamedia
Media type term unmediated
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Source rdamedia
Media type term computer
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Source rdacarrier
Carrier type term volume
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Source rdacarrier
Carrier type term computer disc
347 ## - DIGITAL FILE CHARACTERISTICS
Source rda
File type text file
Encoding format PDF
500 ## - GENERAL NOTE
General note Faculty of Chemical and Process Engineering Technology
502 ## - DISSERTATION NOTE
Dissertation note Thesis (Doctor of Philosophy) -- Universiti Malaysia Pahang – 2023
504 ## - BIBLIOGRAPHY, ETC. NOTE
Bibliography, etc. note Includes bibliographical references
520 3# - SUMMARY, ETC.
Summary, etc. Various methods have been studied for the treatment of Palm Oil Mill Effluent (POME). However, not all of the treatment methods are suitable and efficient in POME treatment. The Upflow Anaerobic Sludge Blanket (UASB) reactor could be utilised to treat a high-strength wastewater such as POME and a higher Chemical Oxygen Demand (COD) removal efficiency and a good methane production rate could be achieved. In the anaerobic digestion of POME, optimum pH should be maintained to ensure the anaerobic process degrades organic matter effectively. The potential of utilizing waste into suitable buffering solutions or neutralization agent could lead to an inexpensive and economically viable approach. To date, there is still a lack of research discussing the potential of using waste cockle shells as a neutralization agent for POME treatment. Thus, this study is designed to evaluate the impact of adding a buffering solution containing calcium oxide (CaO) derived from waste cockle shells on the performance of the continuous UASB reactor treating POME. Overall, four phases were involved in achieving the main objective; i) establishing the correlation between calcination’s operating parameters of waste cockle shells and CaO yield. ii) study the impact of adding calcined cockle shells (CCS) on biomethane production and anaerobic treatability of synthetic wastewater and POME .iii) a kinetic and microbial study was conducted on the UASB reactor treating POME with the addition of CCS. iv) evaluating the biohydrogen production via a dry reforming (DR) process fed with biomethane produced from anaerobic digestion of POME in the continuous UASB reactor. Once the calcination’s operating parameters of obtaining the CCS containing the highest CaO (temperature 900°C, 97.57% CaO) were established, the CCS was dissolved in water (between 1 and 15 g/L concentrations) before the utilization as a buffering solution in the anaerobic digestion of POME. The impact of adding CCS in various concentrations during the anaerobic digestion of POME in the UASB reactor operated at various organic loading rate (OLR) (0.3 to 13.4 g COD/L.day), hydraulic retention time (HRT) (1 to 6 day) and different temperature (28 and 38ºC) fed with i) synthetic wastewater containing chemical oxygen demand (COD) concentrations between 1,665 and 3,416 mg/L, ii) POME with COD concentrations of 1030 and 40,460 mg/L was evaluated. The impact of adding CCS in comparison with commercial Na2CO3 was also determined. The result indicated that adding CCS during the anaerobic digestion of synthetic wastewater has enhanced the COD removal up to 92.35% compared with commercial Na2CO3 (79.36%). In comparison with the UASB reactor treating synthetic wastewater, the utilization of CCS in treating POME has improved the COD removal at about 6% (98% compared to 92%) and promoted the continuous production of biogas between 14 and 22 L/d at OLR of 7 to 14 g COD/L.day. As for synthetic wastewater, minimal biogas production was recorded. The biokinetic parameters evaluated on the UASB reactor treating POME with the addition of CCS were the growth yield (YG), 3.906 g VSS/g CODremoved.d; the specific biomass decay (b), 0.233 d-1; the specific biomass growth rate (μmax), 1.861 d-1; and the saturation constant (Ks), 3.459 g-COD/L. Using the 16S ribosomal ribonucleic acid (rRNA) cloning technique, the genus methanosarcina and methanosaeta were dominant methanogens found in both feeding schemes in the UASB reactor. Overall, the microbial population (Bacteria and Archaea) in POME as the substrate is more diverse than synthetic wastewater due to the abundance of microorganism population in raw POME, which was used as a substrate. The result also shows that the dry reforming converted biogas into 83 % of H2, and 100% CH4 conversion was recorded. In conclusion, using CCS as a buffering solution has proven to improve the anaerobic digestion of POME in a continuous UASB reactor in terms of COD removal efficiency and the biogas production rate. The evaluated biokinetic parameters could be utilized for predicting the performance of the anaerobic digestion of POME using the UASB reactor. The potential of using molecular biology techniques to provide a detailed profile of the microbial community structure will enhance the optimization of treatment processes and eventually produce acceptable effluent quality.
610 20 - SUBJECT ADDED ENTRY--CORPORATE NAME
Corporate name or jurisdiction name as entry element Faculty of Chemical and Process Engineering Technology
General subdivision Dissertations
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Universities and colleges
General subdivision Dissertations
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Theses
942 ## - ADDED ENTRY ELEMENTS (KOHA)
Source of classification or shelving scheme Library of Congress Classification
Koha item type Thesis
Holdings
Withdrawn status Lost status Source of classification or shelving scheme Damaged status Not for loan Collection Home library Current library Date acquired Total checkouts Full call number Barcode Date last seen Copy number Price effective from Koha item type
  Not lost Library of Congress Classification   Not for loan Reference UMPLIB PEKAN UMPLIB PEKAN 22/08/2023   FTKKP .M65 2023 r Thesis T000002497 22/08/2023 1 22/08/2023 Thesis
  Not lost Library of Congress Classification   Final Processing Reference UMPLIB PEKAN UMPLIB PEKAN 22/08/2023   CD13417 T000002498 22/08/2023 1 22/08/2023 Thesis

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