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Effect of zeolitic imidazolate framework-8 and multi-walled carbon nanotube on the performance of pvdf membrane / Nurul Hazreen Wanie Hazmo

By:

Nurul Hazreen Wanie Hazmo [author.]

Material type: Text

text
text

Media type:

unmediated
computer

Carrier type:

volume
computer disc

ISBN:

THE0009135(Local)

Subject(s):

Dissertation note: Thesis (Master of Science) -- Universiti Malaysia Pahang – 2020 Abstract: The main concern in membrane technology is the membrane fouling, which occurs during the filtration process, causing a reduction in water flux and deteriorates the stable performances of membrane filtration system. Several approaches were introduced to eliminate the organic fouling including the incorporation of nanoparticles into a polymer membrane such as silver nanoparticles (AgNPs), zinc oxide (ZnO), zeolitic imidazolate frameworks (ZIFs) and carbon nanotubes (CNTs). Therefore, the synthesized zeolitic imidazolate framework 8 (ZIF-8) and multi-walled carbon nanotubes (MWCNTs) were used as inorganic additives in this work with composition of 0.1wt.%, 0.3wt.% and 0.5wt.%, respectively. The preparation of polyvinyldifluoride (PVDF) membranes was done via physical blending method. The prepared membranes were then characterized by using scanning electron microscopy (SEM), energy dispersive x-ray spectrometry (EDX), and contact angle analysis to investigate their structures in terms of morphology and hydrophilicity properties. Water permeability and filtration performance test were performed using pure water, bovine serum albumin (BSA) and humic acid (HA) solution to evaluate the fouling resistance of the prepared membranes. Even though the fluxes decreased over time, it was found that the ZIF-8/PVDF membrane with 0.5 wt.% concentration has the highest percentage of solute rejection for both BSA (>92%) and HA (>94%) solution as compared to MWCNT/PVDF membranes and pure PVDF membrane. Overall, the nanocomposite membranes showed an improvement in the hydrophilicity, permeability, and solutes rejection rate compared to pristine PVDF membrane. The anti-fouling properties of nanocomposite membranes also has been enhanced with higher flux recovery rate values and lower flux decline rate were achieved as compared to pristine PVDF membrane

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Holdings ( 2 )
Title notes ( 4 )

Holdings
Item type	Current library	Collection	Call number	Copy number	Status	Date due	Barcode
Thesis	UMPLIB GAMBANG Reference	Reference	CD12841 (Browse shelf(Opens below))	1	Not for loan		T000001350
Thesis	UMPLIB GAMBANG Reference	Reference	FTKKP .H39 2020 r Thesis (Browse shelf(Opens below))	1	Not for loan		T000001349

Faculty of Chemical and Process Engineering Technology

Thesis (Master of Science) -- Universiti Malaysia Pahang – 2020

Includes bibliographical references

The main concern in membrane technology is the membrane fouling, which occurs during the filtration process, causing a reduction in water flux and deteriorates the stable performances of membrane filtration system. Several approaches were introduced to eliminate the organic fouling including the incorporation of nanoparticles into a polymer membrane such as silver nanoparticles (AgNPs), zinc oxide (ZnO), zeolitic imidazolate frameworks (ZIFs) and carbon nanotubes (CNTs). Therefore, the synthesized zeolitic imidazolate framework 8 (ZIF-8) and multi-walled carbon nanotubes (MWCNTs) were used as inorganic additives in this work with composition of 0.1wt.%, 0.3wt.% and 0.5wt.%, respectively. The preparation of polyvinyldifluoride (PVDF) membranes was done via physical blending method. The prepared membranes were then characterized by using scanning electron microscopy (SEM), energy dispersive x-ray spectrometry (EDX), and contact angle analysis to investigate their structures in terms of morphology and hydrophilicity properties. Water permeability and filtration performance test were performed using pure water, bovine serum albumin (BSA) and humic acid (HA) solution to evaluate the fouling resistance of the prepared membranes. Even though the fluxes decreased over time, it was found that the ZIF-8/PVDF membrane with 0.5 wt.% concentration has the highest percentage of solute rejection for both BSA (>92%) and HA (>94%) solution as compared to MWCNT/PVDF membranes and pure PVDF membrane. Overall, the nanocomposite membranes showed an improvement in the hydrophilicity, permeability, and solutes rejection rate compared to pristine PVDF membrane. The anti-fouling properties of nanocomposite membranes also has been enhanced with higher flux recovery rate values and lower flux decline rate were achieved as compared to pristine PVDF membrane