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    <subfield code="a">Interfacial microstructure growth mechanism of lead-free solder using laser soldering /</subfield>
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    <subfield code="a">According to scientific evidence, plumbum (Pb) is recognized as a metal with the highest  potential for adverse impacts on human health. For that, there was a growing emphasis  on green electronics, particularly advanced electronic packaging technology, to promote  societal health. As we know, green alloys are considered a safer option for the  environment and human health. These alloys are also recognized for their potential for  reuse, resulting in cost-effectiveness. This study aims to investigate the impact of  different compositions of green solder alloys on the development and growth of  intermetallic compounds (IMC) during laser soldering of a metallized copper substrate.  Besides that, the solder joint strength was analyzed through mechanical testing. The  experiment used Sn and Cu powder with different percentages (Sn-xCu, where x = 0.0,  0.3, 0.5, 0.7, 1.0). In this study, the process starts with materials preparation through  powder metallurgy process route. Powder material was weighed and then blended using  powder milling at the speed range of 1300-1500 rpm for 3 hours. The mixture of powders  was compacted using a pressure of 5 tons to produce thin rectangular pallets with  dimensions of 3.2 x 1.5 mm. These pallets were then subjected to laser soldering using a  CO2 gas laser, with a laser power of 35 watts, a scanning time of 0.04s, a focal length of  40mm, and a scanning speed of 100mm/s. The substrate employed in the experiment was  electroless nickel immersion gold (ENIG). The procedure was further followed by  subjecting the samples to isothermal ageing at a temperature of 150o C for durations of 0,  200, 500, 1000, and 2000 hours. After that, these samples were mechanically tested using  a shear test, following the ASTM D1002 standard was used to evaluate single-lap-joint  adhesively bonded metal specimens (solder alloy). The composition, thickness, and  morphology of IMC formed after laser soldering were examined using various material  characterization techniques, such as optical and image analysis, scanning electron  microscopy, and energy-dispersive X-ray analysis. The study found that the material  composition affected the morphology of IMCs, which also influenced their growth  behaviour. Increasing the Cu content in the solder alloy decreased the thickness of the  IMC, with the lowest thickness observed at 0.3wt% Cu. Nevertheless, the thickness  gradually increased with isothermal ageing, and the IMC changed from a needle-shape  to a continuous level-off shape. The 0.7wt% Cu solder exhibited the lowest diffusion  coefficients and the most effective reduction in IMC growth. The wetting behaviour of  Sn-xCu composite solders was significantly affected by Cu particle content, with the  lowest wetting angle observed at 0.7wt% Cu. Adding Cu to the solder alloy improved the  shear strength of single lap joints, with the highest strength observed at 0.7wt% Cu.  However, the shear strength of Sn-0.3Cu joints decreased after isothermal ageing. The  combination of powder metallurgy and laser soldering techniques improved the reliability  of solder joints in microelectronic production, providing a potential solution for achieving  reliability in microelectronic production processes. The study's results demonstrate the  effectiveness of this approach in achieving a uniform composition and microstructure of  the solder preform, resulting in a superior solder joint with improved mechanical and  thermal properties.</subfield>
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