03735nam a2200265 a 4500 vtls000033121 KUKTEM 20251117145252.0 081128t2008 njua f b 001 0 eng d 0470262028 9780470262023 201107132100 VLOAD 200908141539 VLOAD 200908141510 VLOAD 200908132040 VLOAD 200811281505 farina UMP QD505 .S95 2008 Swiegers, Gerhard F. Mechanical catalysis : methods of enzymatic, homogeneous, and heterogeneous catalysis / Gerhard F. Swiegers Hoboken, N.J. : John Wiley, c2008 xxx, 351 p. : ill. ; 25 cm. Includes bibliographical references and index Introduction to thermodynamic (energy-dependent) and mechanical (time-dependent) processes : What are they and how are they manifested in chemistry and catalysis? / Gerhard F. Swiegers -- Heterogeneous, homogeneous, and enzymatic catalysis ; A shared terminology and conceptual platform ; The alternative of time-dependence in catalysis / Gerhard F. Swiegers -- A conceptual description of energy-dependent ("Thermodynamic") and time-dependent ("Mechanical") processes in chemistry and catalysis / Gerhard F. Swiegers -- Time-dependence in heterogeneous catalysis ; Sabatier's principle describes two independent catalytic realms: time-dependent ("Mechanical") catalysis and energy-dependent ("Thermodynamic") catalysis / Gerhard F. Swiegers -- Time-dependence in homogeneous catalysis. 1. Many enzymes display the hallmarks of time-dependent ("Mechanical") catalysts ; Nonbiological homogeneous catalysts are typically energy-dependent ("Thermodynamic") catalysts / Robin Brimblecombe, Jun Chen, Junhua Huang, Ulrich T. Mueller-Westerhoff, and Gerhard F. Swiegers -- Time-dependence in homogeneous catalysis. 2. The general actions of time-dependent ("Mechanical") and energy-dependent ("Thermodynamic") catalysts / Robin Brimblecombe, Jun Chen, Junhua Huang, Ulrich T. Mueller-Westerhoff, and Gerhard F. Swiegers -- Unifying the many theories of enzymatic catalysis ; Theories of enzymatic catalysis fall into two camps: energy-dependent ("Thermodynamic") and time-dependent ("Mechanical") catalysis / Gerhard F. Swiegers -- Synergy in heterogeneous, homogeneous, and enzymatic catalysis ; The "Ideal" catalyst / Gerhard F. Swiegers -- A conceptual unification of heterogeneous, homogeneous, and enzymatic catalysis / Gerhard F. Swiegers -- The rational design of time-dependent ("Mechanical") homogeneous catalysts ; A literature survey of multi-centered homogeneous catalysis / Junhua Huang, and Gerhard F. Swiegers -- Time-dependent ("Mechanical") nonbiological catalysis. 1. A fully-functional mimic of the water-oxidizing center (WOC) in photosystem II (PSII) / Robin Brimblecombe, G. Charles Dismukes, Greg A. Felton, Leone Spiccia, and Gerhard F. Swiegers -- Time-dependent ("Mechanical") nonbiological catalysis. 2. Highly efficient, "Biomimetic" hydrogen-generating electrocatalysts / Jun Chen, Junhua Huang, Gerhard F. Swiegers, Chee O. Too, and Gordon G. Wallace -- Time-dependent ("Mechanical") nonbiological catalysis. 3. A readily prepared, convergent, oxygen-reduction electrocatalyst / Jun Chen, Gerhard F. Swiegers, Gordon G. Wallace, and Weimin Zhang -- Appendix A. Why is saturation not observed in catalysts that display conventional kinetics -- Appendix B. Graphical illustration of the processes involved in the saturation of molecular catalysts Heterogeneous catalysis Catalysis Enzymes Biotechnology 0 0 0 0 10000 10000 2019-09-04 356.82 0 QD505 .S95 2008 0000036271 2019-09-04 00:00:00 1 356.82 2019-09-04 OPEN VIRTUA40 42776 42782 VTLSSORT0080*0200*0201*0400*0900*1000*2450*2600*3000*5040*5050*6500*6501*6502*9991