TY - BOOK AU - Yang,Jaemoon TI - Six-membered transition states in organic synthesis SN - 0470178833 PY - 2008/// CY - Hoboken, N.J. PB - Wiley-Interscience KW - Reaction mechanisms (Chemistry) KW - Stereochemistry KW - Organic compounds KW - Synthesis N1 - ON ORDER; Includes bibliographical references and indexes; [3,3]-Sigmatropic rearrangements. Claisen rearrangement ; Johnson-Claisen rearrangement ; Ireland-Claisen rearrangement ; Cope rearrangement ; Anionic oxy-Cope rearrangement ; Aza-Cope-Mannich reaction -- Aldol reactions. Asymmetric syn-Aldol reaction ; Asymmetric anti-Aldol reaction ; Proline-catalyzed asymmetric Aldol reaction -- Metal allylation reactions. Boron allylation reaction ; Silicon allylation reaction -- Stereoselective reductions. Diastereoselective syn-reduction of [beta]- hydroxy ketones ; Diastereoselective anti-reduction of [beta]-hydroxy ketones ; Asymmetric reduction ER -