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020 _aTHE0010191(Local)
_qHardback
040 _aUMPSA
_beng
_cUMPSA
_erda
090 _aFTKKP .A55 2025 r Thesis
100 0 _aNur Anis Alisya Binti Kamarol Zani,
_eauthor.
245 1 0 _aBehaviour of carrageenan solution linking to biocomposite properties /
_cNur Anis Alisya Binti Kamarol Zani
264 1 _aKuantan, Pahang :
_bUMPSA,
_c2025
264 4 _c© 2025
300 _axiv, 122 pages :
_billustrations (some color) ;
_c30 cm. +
_e1 CD-ROM
336 _2rdacontent
_atext
337 _2rdamedia
_aunmediated
338 _2rdacarrier
_avolume
347 _2rda
_atext file
_bPDF
500 _aFaculty of Chemical and Process Engineering Technology
502 _aThesis (Master of Science) -- Universiti Malaysia Pahang – 2025
504 _aIncludes bibliographical references
520 3 _aThe behavior of carrageenan solutions plays a crucial role in determining the properties of biocomposite materials. However, there is a lack of comprehensive research on the optimal formulation of carrageenan gels for aromatherapy and food packaging applications. This study investigates the effects of adding salts calcium chloride dihydrate (CCD) and microcrystalline cellulose (MCC) in carrageenan gels, along with the use of plasticizers in carrageenan-PLA films. The aim is to explore how these additives influence the rheological properties, Bloom gel strength, thermal properties, morphology, odor sensory evaluation, and chemical diffusion of carrageenan gels. Carrageenan is known for its gel-forming ability, making it suitable for both aromatherapy and gel-based applications due to its biocompatibility and ability to retain aromatic compounds. This study fills the gap by providing a detailed analysis of carrageenan-based systems that combine desirable gel characteristics with practical applications. The research employed where the concentration of CCD and MCC in carrageenan gels was varied, and rheological measurements were conducted. For the carrageenan-PLA films, different concentrations of polyethylene glycol (PEG) were tested to determine the effects on mechanical properties, water vapor permeability (WVP), and thermal behavior. Results indicated that both the carrageenan gel and carrageenan-PLA formulations exhibited non-Newtonian pseudoplastic behavior. The addition of CCD reduced viscosity and shear stress, with the highest viscosity recorded at 597.84 mPa.s for the gel with 0% CCD. The gelation process accelerated with higher CCD concentrations, and the gel with 2% CCD achieved the highest Bloom gel strength (1324.59 g). Thermal stability and residual weight measurements showed that the gel with 2% CCD maintained its integrity as a long-lasting product. Furthermore, the addition of 0.5% MCC improved the Bloom strength and thermal stability of the gel. In carrageenan-PLA films, 1% PEG showed optimal tensile strength (72.42 MPa), elongation (35.19%), and WVP (4.24 × 10⁻¹⁰ g·m⁻¹·s⁻¹·Pa⁻¹), making it ideal for food packaging applications. The findings highlight the importance of selecting appropriate additives to enhance the functionality of carrageenan gels and films for both aromatherapy and food packaging purposes.
610 2 0 _aFaculty of Chemical and Process Engineering Technology
_xDissertations
650 0 _aUniversities and colleges
_xDissertations
650 0 _aTheses
_xDissertations
942 _2lcc
_cTHESIS
999 _c103810
_d103816