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020 _aTHE0010477 (Local)
_qHardback
040 _aUMPSA
_beng
_cUMPSA
_erda
090 _aFIST .Y44 2025 r Bc.
100 1 _aHeg, Yee Wern,
_eauthor.
245 1 0 _aSynthesis of pyrazoline based compound and computational docking simulation for potential treatment of congestive heart failure /
_cHeg Yee Wern
264 1 _aKuantan, Pahang :
_bUMPSA,
_c2025
264 _c© 2025
300 _axvi, 80 pages :
_billustrations ;
336 _2rdacontent
_atext
337 _2rdamedia
_aunmediated
338 _2rdacarrier
_avolume
347 _2rda
_atext file
_bPDF
500 _aFaculty of Industrial Sciences and Technology
502 _aFinal Year Report (Bachelor of Applied Science of Industrial Chemistry) -- Universiti Malaysia Pahang Al-Sultan Abdullah - 2025
504 _aInclude bibliographical reference
520 3 _aThe study aimed to synthesize a new pyrazoline-based compound and evaluate its potential as a therapeutic agent for congestive heart failure. In the first phase, the pyrazoline-based compound was synthesized via Aldol condensation and Michael addition reaction. The final structure of the synthesized compound was characterized by using spectroscopic techniques. FTIR analysis revealed disappearing key functional group signal including α,β-unsaturated ketone C=O at 1678.40 cm-1 , confirming Aldol condensation was successful. H 1 and C13 NMR further supported the structure with a singlet at 6.32 ppm for N-H proton and multiplet at 7.20-7.40 ppm for aromatic protons. In C13 NMR, the N-C carbon appeared at 131.35 ppm and 134.5 ppm , while aromatic carbons were observed in the range of 129.60-131.24 ppm. Furthermore, in the second phase, the synthesized compound was subjected to in silico molecular docking study targeting four key cardiovascular enzymes—MAPK14, MMP9, NFKBIA and PTGS2. This study is aimed to analyze protein-ligand interactions and evaluate the compound’s potential as a therapeutic agent for heart failure. The result revealed that the synthesized pyrazoline-based compound exhibit higher binding affinities (-6.648 kcal/mol, -6.453 kcal/mol, -5.929 kcal/mol and -7.083 kcal/mol ) compared to captopril (-4.268 kcal/mol, -4.839 kcal/mol, -4.160 kcal/mol and -4.874 kcal/mol ), though the binding affinity is slightly lower than co-crystal standard (-7.611 kcal/mol, -7.138 kcal/mol, -5.235 kcal/mol and -5.780 kcal/mol ). These findings highlighted the potential of the synthesized compound for further development and the potential of PTGS2 protein to be a more pronounce target protein for synthesized pyrazoline-based compound. The interaction was mediated primarily by hydrogen bonding with the essential amino acid residue LUE145, PHE142 and TRP139 and stacking interaction with PHE142 Finally, the preliminary findings indicated that the newly synthesized pyrazoline-bas
610 2 0 _aFaculty of Industrial Sciences and Technology
_xDissertations
650 0 _aUniversities and colleges
_xDissertations
650 0 _aTheses
_xDissertations
856 _uhttps://umpir.ump.edu.my/id/eprint/46104
942 _2lcc
_cPSM
999 _c104755
_d104761