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020 _aTHE0010494 (Local)
_qHardback
040 _aUMPSA
_beng
_cUMPSA
_erda
090 _aFIST .J34 2025 r Bc.
100 1 _aChan, Jun Jie,
_eauthor.
245 1 0 _aDirect valorization of cellulose to glycolic ACID through green heteropoly ACID catalyst supported on tin (iv) oxide /
_cChan Jun Jie
264 1 _aKuantan, Pahang :
_bUMPSA,
_c2025
264 4 _c© 2025
300 _axviii, 104 pages :
_billustrations ;
336 _2rdacontent
_atext
337 _2rdamedia
_aunmediated
338 _2rdacarrier
_avolume
347 _2rda
_atext file
_bPDF
500 _aFaculty of Industrial Sciences and Technology
502 _aFinal Year Report (Bachelor of Applied Science of Industrial Chemistry) -- Universiti Malaysia Pahang Al-Sultan Abdullah - 2025
504 _aInclude bibliographical reference
520 3 _aThis study focuses on the catalytic conversion of cellulose, a renewable and abundant component of lignocellulosic biomass, into glycolic acid, a valuable compound with wide industrial applications. Using phosphomolybdic acid (PMA) supported on tin (IV) oxide (SnO₂) as a heterogeneous catalyst, the research investigates the optimization of glycolic acid synthesis under mild reaction conditions. The study explores the influence of PMA loading on the physicochemical properties of the catalyst and evaluates its catalytic performance in the presence of hydrogen peroxide (H₂O₂) as an oxidant. Characterization techniques such as FTIR, XRD, FESEM-EDS, N₂-physisorption and pyridine adsorption reveal the role of PMA in enhancing surface area, acidity, catalytic efficiency and active sites. The optimized process achieves a high glycolic acid yield of approximately 60% with minimized by-products, demonstrating the bifunctional catalytic behavior of PMA for acid hydrolysis and oxidative cleavage. Systematic parameter studies highlight the importance of reaction time, pH, and oxidant concentration in maximizing yield and selectivity. Additionally, the study confirms the reusability and stability of the PMA/SnO₂ catalyst, showcasing its potential for scalable and sustainable industrial applications. Recommendations for future work include exploring alternative cellulose sources, employing advanced characterization techniques, testing other green oxidants, and conducting reproducibility experiments to validate data. This research contributes to the development of efficient and environmentally friendly processes for biomass valorization, aligning with global sustainability goals.
610 2 0 _aFaculty of Industrial Sciences and Technology
_xDissertations
650 0 _aUniversities and colleges
_xDissertations
650 0 _aTheses
_xDissertations
856 _uhttps://umpir.ump.edu.my/id/eprint/46155
942 _2lcc
_cPSM
999 _c104772
_d104778