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020 _aTHE0010983 (Local)
_qHardback
040 _aUMPSA
_beng
_cUMPSA
_erda
090 _aFSTI .A77 2025 r Bc.
100 0 _aMuhammad Arsyad Bin Mansor, , ,
_eauthor.
245 1 0 _aProduction of superbiochar from palm oil waste for carbon dioxide adsorption /
_cMuhammad Arsyad Bin Mansor
264 1 _aKuantan, Pahang :
_bUMPSA,
_c2025
264 4 _c© 2025
300 _axi, 67 pages :
_billustrations ;
336 _2rdacontent
_atext
337 _2rdamedia
_aunmediated
338 _2rdacarrier
_avolume
347 _2rda
_atext file
_bPDF
500 _aFaculty of Industrial Sciences and Technology
502 _aFinal Year Report Bachelor Of Applied Science In Material Technology (Hons) ) -- Universiti Malaysia Pahang Al-Sultan Abdullah - 2025
504 _aInclude bibliographical reference
520 3 _aThe purpose of this study was to fabricate and characterize thin film copper (Cu)-doped TiO₂ photocatalysts and assess their abilities to degrade methylene blue (MB) dye. Photocatalysis was performed using an ultraviolet (UV) lamp simulating sunlight at 1 Sun (1000 W/m²). Thin films were synthesized with varying doping concentrations of Cu (0 to 6 mol%) and deposited on fluorine doped tin oxide (FTO) coated glass slides with a set active area of 1 cm². A model pollutant solution was assessed utilizing an aqueous MB solution (10 ppm, 8 mL) for degradation experiments taken at 0, 15, 30, 45, and 60 minutes. Absorbance spectra were recorded using the Shimadzu UV-2600 spectrophotometer to assess degradation efficacy and optical bandgaps were determined using the Tauc plot using an indirect transition assumption. The results show that doping with 3 mol% Cu yielded the best performance where degradation time was decreased by 52.49% when compared to control. Degradation followed pseudo-first order kinetics with R² ≈ 1 and the optimal doping concentration determined by second order polynomial regression was about 2.84 mol%. Stability results determined the films maintained their integrity physically post-use. The crystal structure and phase composition of the Cu-doped TiO₂ thin films was analyzed by X-ray diffraction (XRD). The XRD results proved the preservation of anatase phase in all doping concentrations and observable peak shifts signifying the lattice distortion via the process of substitutional insertion of Cu²⁺ ions. However, in further studies nanoscale TiO₂ and hydrothermally grown mesoporous structures like nanopillars would provide a better static active surface area. The developed system is applicable for further uses in fertilizer, pesticide, and detergent degradation as well as oil degradation and bacterial reduction in water treatment.
610 2 0 _aFaculty of Industrial Sciences and Technology
_xDissertations
650 0 _aUniversities and colleges
_xDissertations
650 0 _aTheses
_xDissertations
856 _uhttps://umpir.ump.edu.my/id/eprint/46313
942 _2lcc
_cPSM
999 _c105491
_d105497