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008 100128t2009 my a f m 000 0 eng|d
020 _aTHE0003614(Local)
039 9 _a201905152050
_bzulaiha
_c201108031256
_dFida
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_dVLOAD
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040 _aUMP
090 _aTK2931 .A93 2009 rs Bc.
100 0 _aMohd Norazam Md Aris
245 1 0 _aDevelopment and characterization of sulfonated polyethersulfone for proton exchanfe membrane fuel cell application/
_cMohd Norazam Md Aris
246 3 _aDevelopment and characterization of sulfonated polyethersulfone for proton exchanfe membrane fuel cell application
_h[computer file]
260 _aKuantan, Pahang :
_bUMP,
_c2009
300 _a47 p. :
_bill. (some col.) ;
_c30 cm. +
_e1 computer disc
502 _aProject paper (Bachelor of of Chemical engineering (Gas Technology)) -- Universiti Malaysia Pahang - 2009
504 _aIncludes bibliographical references
520 3 _aSulfonated polyethersulfone (SPES) with 20% concentration by weight were prepared with concentrated sulfonic acid at room temperature. Membrane solution developed in this study consisted of polyethersulfone dissolved in N,N – Dimethylformamide (DMF) as solvent, fuming sulfuric acid (36%) and concentrated sulfuric acid (95%-97%) as the sulfonating agent. The solution was cast manually at temperature between 25oC-28 oC. The investigation on water uptake, TGA, CHNOS elemental analysis, and FTIR has been conducted. Successful introduction of the sulfonated groups was confirmed by using the FTIR spectra in the wave number range 1020cm-1-1030 cm-1 which attributed to the symmetrical stretch of the sulfonated group. It was found that sulfonated membrane produced from mixed sulfonating agent (98% H2SO4 and 36% H2SO4.SO3) have higher degree of swelling. The type and ratio of the sulfonating agent has been identified as one of the most influential parameter in determining the bonding of -HCO3 as well as the membrane performance thus, producing different morphology. The parameter such as sulfonating agent ratio and type used strongly affects the membrane performance. -Author-
650 0 _aProton exchange membrane fuel cells
_xDesign and construction
650 0 _aElectrochemistry
650 0 _aMembranes (Technology)
999 _aVIRTUA40
_c1676
_d1682
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