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005 20251114204459.0
008 180924t20182018my a f a m 001 0 eng d
020 _aTHE0000993(Local)
039 9 _a201905241634
_bnazirah
_y201809241056
_zfateeha
040 _aUMP
_beng
_cUMP
_erda
090 _aFKKSA .R33 2018 r Thesis
100 0 _aRabiatuladawiah Mahmod,
_eauthor.
245 1 0 _aPreparation and characterization of poly(MMA-CO-EGDMA-CO-VBC) via photoinitiated dispersion polymerization route to sulfonated hypercrosslinked resin /
_cRabiatuladawiah Mahmod
264 1 _aKuantan, Pahang :
_bUMP,
_c2018
264 4 _c© 2018
300 _axv, 118 pages :
_billustrations (some color) ;
_c30 cm. +
_e1 CD-ROM
336 _atext
_2rdacontent
336 _atext
_2rdacontent
337 _aunmediated
_2rdamedia
337 _acomputer
_2rdamedia
338 _avolume
_2rdacarrier
338 _acomputer disc
_2rdacarrier
347 _atext file
_bPDF
_2rda
500 _aFaculty of Chemical and Natural Resources Engineering
502 _aThesis (Master of Science) -- Universiti Malaysia Pahang – 2018
504 _aIncludes bibliographical references
520 3 _aA sulfonated hypercrosslinked polymer resin was derived from poly(MMA-co-EGDMA-co-VBC) polymer. In the present study, the sulfonated hypercrosslinkedpolymer resin was synthesized via two stages; photoinitiated dispersion polymerization employed to synthesis polymer precursor and post-polymerization which involved hypercrosslinking reaction and functionalization reaction to obtained sulfonated resin. In the first stage (photoinitiated dispersion polymerization) was conducted to counter the problems regarding the method of conventional dispersion polymerization in terms of the disturbance of functional reagents during nucleation stage. In this stage, which was the preliminary stage of the study, several parameters had been investigated: types of monomer, types of photoinitiators (PI), reaction times, and the amount of crosslinker, co-monomer, stabilizer as well as solvent/porogen ratio. In a screening test using a full factorial design of experiment (DoE), a 24 full factorial design was used to determine the significant parameters that could affect the yield of polymer precursor obtained in terms of the amounts of crosslinker, co-monomer, PI and also reaction times. The DoE analysis showed that the most significant factor was the reaction times. For further optimization study, central composite design (CCD) approach were design using the factor the amounts of crosslinker, co-monomer and PI were chosen as parameters in order to obtain high yield and good quality of polymer precursor. In the second stage (post-polymerization), the optimized precursor underwent two approaches which is hypercrosslinking reaction was conducted first before functionalization reaction and second approach hypercrosslinking reaction conducted after functionalization. Both approaches were conducted to overcome the low specific surface area (SSA) of sulfonated resin. The characterizations involved were the scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), X-ray fluorescence (XRF), CHNS analysis, Brunauer-Emmet-Teller (BET) analysis, particle size distribution (PSD) and thermal gravimetric analysis (TGA) in both stages meanwhile ion exchange capacity (IEC) value, specific surface area, morphology and thermal stability involved in the post-polymerization. In conclusion, the present study has provided significant guidelines and basic understanding of the synthesized sulfonated hypercrosslinked polymer resin derived from poly(MMA-co-EGDMA-co-VBC) polymer. It was found that first approach in post-polymerization resulting higher SSA and IEC value compared to second approach.
610 2 0 _aFaculty of Chemical & Natural Resources Engineering
_xDissertations
650 0 _aUniversities and colleges
_xDisertations
650 0 _aTheses
999 _aVIRTUA40
_c2767
_d2773
999 _aVTLSSORT0080*0200*0400*0900*1000*2450*2640*2641*3000*3360*3361*3370*3371*3380*3381*3470*5000*5020*5040*5200*6100*6500*6501*9992