000 02699nam a2200265 a 4500
001 vtls000067166
003 KUKTEM
005 20251114204530.0
008 121129t2012 my a f m 000 0 eng d
020 _aTHE0004301(Local)
039 9 _a201905161413
_bfarhana
_c201211291650
_dFida
_y201211291649
_zFida
040 _aUMP
090 _aTP242 .Z36 2012 rs Bc.
100 0 _aNik Nur Zanaryah Nik Hassan
245 1 0 _aThe effect of different coupling agent on zeolite modification for development of polyetehersulfone mmms for O2/N2 separation /
_cNik Nur Zanaryah Nik Hassan
260 _aKuantan, Pahang :
_bUMP,
_c2012
300 _axv, 58 p. :
_bill. ;
_c30 cm. +
_e1 CD-ROM
502 _aProject paper (Bachelor of Chemical Engineering (Gas Technology)) -- Universiti Malaysia Pahang - 2012
504 _aBibliography : p. 51-53
520 3 _aThe industrial gas separations have been attracted in using membrane for gas separations since membrane separation technologies have the advantages of energy efficiency, simplicity and low cost. This lead to the exploration mixed matrix membrane (MMMs) that combining the polymeric membrane filled with organics particles. In order to improve the interaction between polymer and zeolite, chemical modification on the surface of zeolite using silane coupling agents need to be done to increase the compatibility between zeolite and polymer. In this study, the effect of difference coupling agents used on zeolite modification in development of Polyethersulfone MMMs for O2/N2 separation was studied. Three types of coupling agents were used which are 3-aminopropyltriethoxysilane, glycidoxypropyltrimethoxysilane and 3aminopropyltrimethoxy- silane (APTMOS). The polymer solution was prepared contains of 30% Polyethersulfone (PES) as the polymer, 55% of N-Methyl Pyrolidone (NMP) as the solvent and 15% of zeolite 5A. The dry/wet phase inversion method was used to produce the membrane. The membrane was coated with silicone and n-hexane in order to decrease the surface defect and tested using O2 and N2 gases to determine the membrane performance. For surface and cross section image of membrane were identified using Scanning Electron Microscope (SEM). Membrane was also characterized using Fourier Transform Infrared Spectroscopy (FTIR) to analyze the presence of silane coupling agent functional group. As a conclusion, the best performance was identified by using glycidoxypropyltrimethoxysilane which gives high selectivity about 3.14.
650 0 _aGases
_xSeparation
650 0 _aGas separation membranes
650 0 _aPolymers
999 _aVIRTUA40
_c3644
_d3650
999 _aVTLSSORT0080*0200*0400*0900*1000*2450*2600*3000*5020*5040*5200*6500*6501*6502*9992