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001			vtls000033121
003			KUKTEM
005			20251117145252.0
008			081128t2008 njua f b 001 0 eng d
020			_a0470262028
020			_a9780470262023
039		9	_a201107132100 _bVLOAD _c200908141539 _dVLOAD _c200908141510 _dVLOAD _c200908132040 _dVLOAD _y200811281505 _zfarina
040			_aUMP
090			_aQD505 .S95 2008
100	1		_aSwiegers, Gerhard F.
245	1	0	_aMechanical catalysis : _bmethods of enzymatic, homogeneous, and heterogeneous catalysis / _cGerhard F. Swiegers
260			_aHoboken, N.J. : _bJohn Wiley, _cc2008
300			_axxx, 351 p. : _bill. ; _c25 cm.
504			_aIncludes bibliographical references and index
505	0		_aIntroduction to thermodynamic (energy-dependent) and mechanical (time-dependent) processes : What are they and how are they manifested in chemistry and catalysis? / Gerhard F. Swiegers -- Heterogeneous, homogeneous, and enzymatic catalysis ; A shared terminology and conceptual platform ; The alternative of time-dependence in catalysis / Gerhard F. Swiegers -- A conceptual description of energy-dependent ("Thermodynamic") and time-dependent ("Mechanical") processes in chemistry and catalysis / Gerhard F. Swiegers -- Time-dependence in heterogeneous catalysis ; Sabatier's principle describes two independent catalytic realms: time-dependent ("Mechanical") catalysis and energy-dependent ("Thermodynamic") catalysis / Gerhard F. Swiegers -- Time-dependence in homogeneous catalysis. 1. Many enzymes display the hallmarks of time-dependent ("Mechanical") catalysts ; Nonbiological homogeneous catalysts are typically energy-dependent ("Thermodynamic") catalysts / Robin Brimblecombe, Jun Chen, Junhua Huang, Ulrich T. Mueller-Westerhoff, and Gerhard F. Swiegers -- Time-dependence in homogeneous catalysis. 2. The general actions of time-dependent ("Mechanical") and energy-dependent ("Thermodynamic") catalysts / Robin Brimblecombe, Jun Chen, Junhua Huang, Ulrich T. Mueller-Westerhoff, and Gerhard F. Swiegers -- Unifying the many theories of enzymatic catalysis ; Theories of enzymatic catalysis fall into two camps: energy-dependent ("Thermodynamic") and time-dependent ("Mechanical") catalysis / Gerhard F. Swiegers -- Synergy in heterogeneous, homogeneous, and enzymatic catalysis ; The "Ideal" catalyst / Gerhard F. Swiegers -- A conceptual unification of heterogeneous, homogeneous, and enzymatic catalysis / Gerhard F. Swiegers -- The rational design of time-dependent ("Mechanical") homogeneous catalysts ; A literature survey of multi-centered homogeneous catalysis / Junhua Huang, and Gerhard F. Swiegers -- Time-dependent ("Mechanical") nonbiological catalysis. 1. A fully-functional mimic of the water-oxidizing center (WOC) in photosystem II (PSII) / Robin Brimblecombe, G. Charles Dismukes, Greg A. Felton, Leone Spiccia, and Gerhard F. Swiegers -- Time-dependent ("Mechanical") nonbiological catalysis. 2. Highly efficient, "Biomimetic" hydrogen-generating electrocatalysts / Jun Chen, Junhua Huang, Gerhard F. Swiegers, Chee O. Too, and Gordon G. Wallace -- Time-dependent ("Mechanical") nonbiological catalysis. 3. A readily prepared, convergent, oxygen-reduction electrocatalyst / Jun Chen, Gerhard F. Swiegers, Gordon G. Wallace, and Weimin Zhang -- Appendix A. Why is saturation not observed in catalysts that display conventional kinetics -- Appendix B. Graphical illustration of the processes involved in the saturation of molecular catalysts
650		0	_aHeterogeneous catalysis
650		0	_aCatalysis
650		0	_aEnzymes _xBiotechnology
999			_aVIRTUA40 _c42776 _d42782
999			_aVTLSSORT0080*0200*0201*0400*0900*1000*2450*2600*3000*5040*5050*6500*6501*6502*9991