000 02026nam a2200265 a 4500
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008 131030t2013 my da f abm 000 0 eng d
020 _aTHE0002129(Local)
039 9 _a201905131649
_byusri
_y201310301439
_znabilah
040 _aUMP
090 _aQD305.A2 T46 2013 rs Bc.
100 1 _aTeoh, Wei How
245 1 0 _aRecovery of dilute acetic acid via esterification reaction catalyzed by Amberlyst 15 /
_cTeoh Wei How
260 _aKuantan, Pahang :
_bUMP,
_c2013
300 _axiii, 57 p. :
_bill. ;
_c30 cm. +
_e1 CD-ROM
502 _aProject paper (Bachelor of Chemical Engineering) -- Universiti Malaysia Pahang – 2013
504 _aBibliography : p. 49-52
520 3 _aThe recovery of acetic acid from its dilute aqueous solutions is a major problem in both petrochemical and fine chemical industries. The conventional physical separations such as distillation and extraction suffer from several drawbacks. In the present work, the esterification reaction of dilute acetic acid with 2-ethyl-1-hexanol has been studied in the presence of ion-exchange resin Amberlyst 15. The effect of important operating parameters such as speed of agitation and reaction temperature has been examined. Within the range of study, the maximum conversion of acetic acid reached 98.8% at temperature of 100°C. For speed of agitation, there is no much effect to the conversion of acetic acid ranging from 300rpm to 600pm where the highest conversion of acetic acid was 75%. Experimental kinetic data of the esterification reaction were correlated with the pseudo-homogeneous (PH), Langmuir-Hinshelwood-Hougen-Watson (LHHW) and Eley-Rideal (ER) models. The LHHW model gave the best agreement with the data. The activation energy for the reaction was found to be 71.08 kJmol-1.
650 0 _aEsterification
650 0 _aAcetic acid
650 0 _aCatalysts
999 _aVIRTUA40
_c4310
_d4316
999 _aVTLSSORT0080*0200*0400*0900*1000*2450*2600*3000*5020*5040*5200*6500*6501*6502*9992