000 02710ntm a2200241 a 4500
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003 KUKTEM
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008 141112t2013 my a f m 000 0 eng d
020 _aTHE0004994(Local)
039 9 _a201905140856
_bSHAHRILJ
_c201411141246
_dfawwaz
_y201411121557
_zfawwaz
040 _aUMP
090 _aTS156.8 .T36 2013 r Bc.
100 0 _aTan, Wooi Chuan
245 1 0 _aModification of titanium dioxide nanoparticle to enhance the photoactivity in visible light region /
_cTan Wooi Chuan
260 _aKuantan, Pahang :
_bUMP,
_c2013
300 _axii, 31 p. :
_bill. ;
_c30 cm. +
_e1 CD-ROM
502 _aProject paper (Bachelor of Chemical Engineering) -- Universiti Malaysia Pahang - 2013
504 _aBibliography : p. 29-31
520 3 _aIn recent year, photocatalyst has been gaining a wide attention as the ability to harness the free energy from sunlight to perform variety of function such as organic degradation, solar cell and etc. When used as photocatalyst, titanium dioxide (TiO2) is able to absorb ultraviolet light only (UV) to initiate the oxidation and reduction which is able to speed up the degradation of dye. This thus provides a cheap and efficient method to solve the dye mismanagement that is face in industries these days. In this work, the titanium dioxide nanoparticle is modified via hydrazine wet method to increase photocatalytic activity. The photocatalytic activity is studied via methylene blue degradation, followed by the kinetic study on the methylene blue degradation. The catalyst has been characterized via UV-VIS spectrophotometer, FTIR machine and XRD machine. From the result, we realized that the main reaction that occurred during the modification is combustion of hydrazine on the surface of TiO2. From the UV-Vis spectrum, we found out that the modify catalyst can absorb more visible light as compare to the commercial TiO2. FTIR spectrum indicated that NHx group, NO group and an increase of OH group is presented after the modification. XRD pattern analysis suggested the crystallinity of the catalyst is slightly increased after the modification. Methylene blue degradation also showed that the modified catalyst have a higher activity as compared to the commercial one. The results obtained suggesting that the photocatalytic activity is increasing due to the ability of the catalyst to absorb visible light after the treatment. The modeling is done by relating the rate of methylene blue degradation with the direct hole attack and the hydroxyl radical attack occurred in the reaction
650 0 _aTitanium dioxide
999 _aVIRTUA40
_c5643
_d5649
999 _aVTLSSORT0080*0200*0400*0900*1000*2450*2600*3000*5020*5040*5200*6500*9992