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003 KUKTEM
005 20251117150452.0
008 100701t2010 nju f b 001 0 eng d
020 _a9780470770832 (hardback)
039 9 _a201107132358
_bVLOAD
_c201011221607
_dfauzi
_y201007011038
_zfaiz
040 _aUMP
090 _aQD471 .S73 2010
245 0 0 _aStable radicals :
_bfundamentals and applied aspects of odd-electron compounds /
_ceditor, Robin Hicks
260 _aHoboken, N.J. :
_bWiley,
_c2010
300 _axviii, 588 p. :
_bill. ;
_c25 cm.
504 _aIncludes bibliographical references and index
520 _a"Stable radicals- molecules with odd electrons which are sufficiently long lived to be studied or isolated using conventional techniques- have enjoyed a long history and are of current interest for a broad array of fundamental and applied reasons, for example to study and drive novel chemical reactions, in the development of rechargeable batteries or the study of free radical reactions in the body. In Stable Radicals: Fundamentals and Applied Aspects of Odd-Electron Compounds a team of international experts provide a broad-based overview of stable radicals, from the fundamental aspects of specific classes of stable neutral radicals to their wide range of applications including synthesis, materials science and chemical biology. Topics covered include: triphenylmethyl and related radicals polychlorinated triphenylmethyl radicals: towards multifunctional molecular materials phenalenyls, cyclopentadienyls, and other carbon-centered radicals the nitrogen oxides: persistent radicals and van der Waals complex dimers nitroxide radicals: properties, synthesis and applications the only stable organic sigma radicals: di-tert-alkyliminoxyls. Delocalized radicals containing the hydrazyl [R2N-NR] unit metal-coordinated phenoxyl radicals stable radicals containing the thiazyl unit: synthesis, chemical, and materials properties stable radicals of the heavy p-block elements application of stable radicals as mediators in living-radical polymerization nitroxide-catalyzed alcohol oxidations in organic synthesis metal-nitroxide complexes: synthesis and magneto-structural correlations rechargeable batteries using robust but redox-active organic radicals spin labeling: a modern perspective functional in vivo EPR spectroscopy and imaging using nitroxides and trityl radicals biologically relevant chemistry of nitroxides. Stable Free Radicals: Fundamentals and Applied Aspects of Odd-Electron Compounds is an essential guide to this fascinating area of chemistry for researchers and students working in organic and physical chemistry and materials science."-- œc Provided by publisher
520 _a"Stable radicals - molecules with odd electrons which are sufficiently long lived to be studied or isolated using conventional techniques - have enjoyed a long history and are of current interest for a broad array of fundamental and applied reasons, for example to study and drive novel chemical reactions, in the development of rechargeable batteries or the study of free radical reactions in the body"-- œc Provided by publisher
650 0 _aRadicals (Chemistry)
_xStability
650 0 _aElectron mobility
700 1 _aHicks, Robin
999 _aVIRTUA40
_c58979
_d58985
999 _aVTLSSORT0080*0200*0400*0900*2450*2600*3000*5040*5200*5201*6500*6501*7000*9991