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008 160404t2015 da f ab m 000 0 eng d
020 _aTHE0000910(Local)
039 9 _a201905271538
_bnazirah
_c201710111634
_daishah
_y201604041443
_zshima
040 _aUMP
090 _aFKKSA .H53 2015 r Thesis
100 0 _aNurul Hidayah Muhamad @ Ghazali
245 1 _aDevelopment of limestone based catalyst for biodiesel production from waste cooking oil/
_cNurul Hidayah Binti Muhamad @ Ghazali
260 _aKuantan, Pahang :
_bUMP,
_c2015
300 _axv, 81 p. :
_bill. (some col.) ;
_c30 cm. +
_e1 CD-ROM
500 _aFaculty of Chemical & Natural Resources Engineering
502 _aThesis (Master of Engineering ( Chemical ) -- Universiti Malaysia Pahang – 2015
504 _aBibliography : p. 67-72
520 3 _aRecent developments in biodiesel production have heightened the need for feasible feedstock as this biofuel has high demands because of its advantages. Besides, catalysts play a significant role in improving production of biodiesel fuel. In addition, the determination catalyst is main important for designing a transesterification system. Industrial production of biodiesel employs homogeneous catalysts such as NaOH or KOH which are cannot be recovered and tolerate to soap formation. Thus, the purpose of this research is to develop and characterize the catalyst derived from limestone based. The effect of various condition i.e. different activation catalysts, temperature, WCO to methanol ratio, catalyst loading, reaction time and recyclability on biodiesel production will be studied. Besides, this research also attempts to utilize waste cooking oil as viable feedstock for biodiesel production. A catalyst produced from cement clinker (limestone based) with particle size of 250μm was prepared via wet impregnation method using aqueous solution of potassium hydroxide (KOH) and calcination. The characterizations of catalysts were done using Hammett indicators, X-Ray Fluorescence, SEM, BET and BJH and the product of biodiesel were determined using GC and HPLC. From this research, it was found that KOH activated limestone based catalyst shows a good potential as an alternate for one-step transesterification of low FFA waste cooking oil. Conventional transesterification of WCO using this activated catalyst was found to give the highest WCO conversion to FAME at 96.8% and FAME yield of 60.4% within 60 min of reaction. The end-product from this research also complies with ASTM Standards D6751. The results suggest that the catalyst employed in this work might be useful as a new low cost catalyst for biodiesel production.
610 2 0 _aFaculty of Chemical & Natural Resources Engineering
_xDissertations
650 0 _aUniversities and Colleges
_xDissertations
650 0 _aTheses
856 4 0 _uhttp://ecollib.ump.edu.my/3559/
_zLibrary access only
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