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008 180122s2017 my a f am 00 0 eng d
020 _aTHE0000876(Local)
039 9 _a201905271450
_bnazirah
_c201802201218
_dsaini
_y201801221154
_zsaini
040 _aUMP
_beng
_cUMP
_erda
090 _aFKKSA .F36 2017 r Bc.
100 1 _aFan, Fu Win,
_eauthor.
245 1 0 _aPlastic to fuel :
_beffect of catalyst support for nickel catalst /
_cFan Fu Win
264 1 _aKuantan, Pahang :
_bUMP,
_c2017
264 4 _c© 2017
300 _axv, 45, [xi] pages :
_billustrations (some color) ;
_c30 cm. +
_e1 CD-ROM
336 _atext
_2rdacontent
336 _atext
_2rdacontent
337 _aunmediated
_2rdamedia
337 _acomputer
_2rdamedia
338 _avolume
_2rdacarrier
338 _acomputer dics
_2rdacarrier
347 _atext file
_bPDF
_2rda
500 _aFaculty of Chemical & Natural Resources Engineering
502 _aProject Paper (Bachelor of Chemical Engineering) -- Universiti Malaysia Pahang – 2017
504 _aIncludes bibliographical references
520 3 _aThe depletion of fossil fuel encourages development of alternative energy resources. Investigation on converting waste to fuel via pyrolysis including plastic waste; one of major waste composition, is recently explored by many researchers. One of the goal of the current researches is to develop a lower cost of catalyst. However, low yield and fuel quality are among major obstacles to scale up this process. The aim of this research is to synthesis, test and characterize nickel catalyst at various supports for plastic to fuel via catalytic pyrolysis. High Density Polyethylene (HDPE) resin was characterized by using Thermogravimetric Analyser (TGA). A 20 wt% of nickel catalyst with either alumina or oil palm ash support was synthesized via wet impregnation. High Density Polyethylene (HDPE) resin was used at a plastic to catalyst weight ratio of 10:1. The catalyst was tested in a batch one litre borosilicate reactor that heated up to 450 C for half an hour. A condenser was used to liquefy the product. Solid, liquid and gas product was obtained. Catalyst pore structure, catalyst surface morphology and composition was determined to characterize the catalyst by using Brunauer, Emmett and Teller (BET) and Scanning electron microscope (SEM) respectively. The uncondensed gas was collected in gas bag. The gas product was analysed by using Gas Chromatography-Thermal Conductivity Detector (GC-TCD). The calorific value, viscosity, clarity and yield of the liquid products was also determined. Gas chromatography-mass spectrometry (GC-MS) was used to determine the liquid fuel composition. The use of ash as a catalyst support for nickel in pyrolysis process has achieved a high liquid product yield of 75.32 wt% and an equivalent quality to that of commercial fuel. Besides, a gas product that rich in hydrogen (66.83 mol%) and methane gas (4.92 mol%) was obtained. Finding from this work is vital for generating cheap catalyst for plastic waste pyrolysis process. In conclusion, cheap and green technology for alternative fuel production via plastic pyrolysis using ash as catalyst support can be commercialized and scale up.
610 2 0 _aFaculty of Chemical & Natural Resources Engineering
_xDissertations
650 0 _aUniversities and Colleges
_xDissertations
650 0 _aTheses
999 _aVIRTUA40
_c7326
_d7332
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